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phenyl hydrazine cas no:100-63-0

Synonyms: Hydrazinobenzene;Monophenylhydrazine;AI3-15399;BRN 0606080;CCRIS 511;Fenilidrazina;Fenilidrazina [Italian];Fenylhydrazine;Fenylhydrazine [Dutch];HSDB 1117;Hydrazine, phenyl-;Hydrazine-benzene;Hydrazobenzene;Phenylhydrazin;Phenylhydrazin [German];Phenylhydrazine [UN2572] [Poison];Phenylhydrazine and its salts;UN2572;

Identification
Namephenyl hydrazine
CAS100-63-0
SynonymsHydrazinobenzene;Monophenylhydrazine;AI3-15399;BRN 0606080;CCRIS 511;Fenilidrazina;Fenilidrazina [Italian];Fenylhydrazine;Fenylhydrazine [Dutch];HSDB 1117;Hydrazine, phenyl-;Hydrazine-benzene;Hydrazobenzene;Phenylhydrazin;Phenylhydrazin [German];Phenylhydrazine [UN2572] [Poison];Phenylhydrazine and its salts;UN2572;
EINECS(EC#)202-873-5
Molecular FormulaC6H8N2
Molecular Weight108.14
Chemical Properties
Appearanceyellow to pale brown oily liquid
refractive index1.604-1.609
storage tempStore at RT.
Sensitive Air & Light Sensitive
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1
Safety Data

Hazard T:Toxic;N:Dangerousfortheenvironment;
Risk R23/24/25;R36/38;R43;R45;R48/23/24/25;R50;R68
Safety

Hazard Codes of Phenylhydrazine (CAS NO.100-63-0):?ToxicT,DangerousN
Risk Statements: 45-23/24/25-36/38-43-48-50-68?
R45: May cause cancer.?
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.?
R36/38: Irritating to eyes and skin.?
R43: May cause sensitization by skin contact.?
R48: Danger of serious damage to health by prolonged exposure.?
R50: Very toxic to aquatic organisms.?
R68: Possible risk of irreversible effects.
Safety Statements: 53-45-61?
S53: Avoid exposure - obtain special instructions before use.?
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 2572 6.1/PG 2
WGK Germany: 3
RTECS: MV8925000
F: 8-10-23
HazardClass: 6.1
PackingGroup: II
Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion, subcutaneous, and intravenous routes. Experimental reproductive effects. Mutation data reported. Ingestion or subcutaneous injection can cause hemolysis of red blood cells. Other effects are damage to the spleen, liver, kidneys, and bone marrow. The most common effect of occupational exposure is the development of dermatitis, which, in sensitized persons, may be quite severe. Systemic effects include anemia and general weakness, gastrointestinal disturbances, and injury to the kidneys. Flammable when exposed to heat, flame, or oxidizers. To fight fire, use alcohol foam. Violent reaction with 2-phenylamino-3-phenyloxazirane. Reacts with perchloryl fluoride to form an explosive product. Vigorous reaction with lead(IV) oxide. Used as a chemical reagent, in organic synthesis, and in the manufacture of dyes and drugs. Dangerous; when heated to decomposition it emits highly toxic fumes of NOx; can react with oxidizing materials.


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo intravenous 120mg/kg (120mg/kg) ? U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 159, 1941.
dog LDLo oral 200mg/kg (200mg/kg) ? U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 159, 1941.
frog LDLo unreported 300mg/kg (300mg/kg) ? U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 159, 1941.
guinea pig LD50 oral 80mg/kg (80mg/kg) BEHAVIORAL: EXCITEMENT

BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)
Hygiene and Sanitation Vol. 30(7-9), Pg. 191, 1965.
mouse LC50 inhalation 2120mg/m3 (2120mg/m3) ? Trudy Leningradskogo Sanitarno-Gigienicheskogo Meditsinskogo Instituta. Vol. 115, Pg. 59, 1977.
mouse LD50 intraperitoneal 170mg/kg (170mg/kg) ? Cancer Research. Vol. 41, Pg. 1469, 1981.
mouse LD50 oral 175mg/kg (175mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(8), Pg. 21, 1965.
mouse LDLo subcutaneous 170mg/kg (170mg/kg) LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LUNGS, THORAX, OR RESPIRATION: CYANOSIS
Journal of Industrial Hygiene and Toxicology. Vol. 18, Pg. 1, 1936.
rabbit LD50 oral 80mg/kg (80mg/kg) BEHAVIORAL: EXCITEMENT

BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)
Hygiene and Sanitation Vol. 30(7-9), Pg. 191, 1965.
rabbit LDLo skin 90mg/kg (90mg/kg) LUNGS, THORAX, OR RESPIRATION: CYANOSIS

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION

KIDNEY, URETER, AND BLADDER: HEMATURIA
National Technical Information Service. Vol. OTS0546542,
rat LC50 inhalation 2610mg/m3 (2610mg/m3) ? Trudy Leningradskogo Sanitarno-Gigienicheskogo Meditsinskogo Instituta. Vol. 115, Pg. 59, 1977.
rat LD50 oral 188mg/kg (188mg/kg) BEHAVIORAL: EXCITEMENT

BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)
Hygiene and Sanitation Vol. 30(7-9), Pg. 191, 1965.

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