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Triphenyl phosphite cas no:101-02-0

Synonyms: Triphenyl Phosphite (TPPi); Triphenyl phospite; Triphenylphosphite white yellow xtl; Triphenyl Phosphine Oxide

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Identification
NameTriphenyl phosphite
CAS101-02-0
SynonymsTriphenyl Phosphite (TPPi); Triphenyl phospite; Triphenylphosphite white yellow xtl; Triphenyl Phosphine Oxide
EINECS(EC#)202-908-4
Molecular FormulaC18H15O3P
Molecular Weight310.29
Chemical Properties
Appearancecolourless to pale yellow liquid
refractive index1.5893-1.5913
storage tempKeep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Sensitive Air & Moisture Sensitive
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass9
Safety Data

Hazard Xi:Irritant;N:Dangerousfortheenvironment;
Risk R36/38;R50/53
Safety

Poison by intraperitoneal and subcutaneous routes. Moderately toxic by ingestion. An experimental eye and severe human skin irritant. Combustible when exposed to heat or flame. To fight fire, use CO2, mist, dry chemical. When heated to decomposition, it emits toxic fumes of POx. See also?Phenol.
Hazard Codes:?HarmfulXnDangerousN,IrritantXi
Risk Statements: 36/38-50/53
R36/38:Irritating to eyes and skin.?
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 28-60-61-28A
S28:After contact with skin, wash immediately with plenty of soap-suds.?
S60:This material and its container must be disposed of as hazardous waste.?
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.?
S28:After contact with skin, wash immediately with plenty of soap-suds.
RIDADR: UN 3077 9/PG 3
WGK Germany: 2
RTECS: TH1575000
HazardClass: 9
PackingGroup: III
HS Code: 29209085


HS Code 29209085

Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo intraperitoneal 100mg/kg (100mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: TREMOR		 National Technical Information Service. Vol. OTS0570901,
cat LDLo subcutaneous 300mg/kg (300mg/kg) BEHAVIORAL: ATAXIA Journal of Pharmacology and Experimental Therapeutics. Vol. 49, Pg. 78, 1933.
chicken LDLo intravenous 50mg/kg (50mg/kg) AUTONOMIC NERVOUS SYSTEM: GAGLION BLOCK Nippon Eiseigaku Zasshi. Japanese Journal of Hygiene. Vol. 44, Pg. 118, 1989.
chicken LDLo oral 250mg/kg (250mg/kg) BEHAVIORAL: ATAXIA National Technical Information Service. Vol. OTS0532280,
chicken LDLo subcutaneous 375mg/kg (375mg/kg) BEHAVIORAL: FOOD INTAKE (ANIMAL)

BEHAVIORAL: ATAXIA		 National Technical Information Service. Vol. OTS0532280,
mammal (species unspecified) LD50 intraperitoneal 250mg/kg (250mg/kg) BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES

CARDIAC: OTHER CHANGES

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD		 AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 5, Pg. 311, 1952.
mouse LD50 intraperitoneal 266mg/kg (266mg/kg) ? Agricultural and Biological Chemistry. Vol. 31, Pg. 1288, 1967.
mouse LD50 oral 1080mg/kg (1080mg/kg) ? Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 31(12), Pg. 53, 1987.
mouse LD50 unreported 1360mg/kg (1360mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: TREMOR

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)		 Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(9), Pg. 55, 1977.
rabbit LDLo skin 5gm/kg (5000mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) National Technical Information Service. Vol. OTS0532280,
rat LC inhalation > 6700mg/m3/1H (6700mg/m3) ? National Technical Information Service. Vol. OTS0532280,
rat LD50 intraperitoneal 250mg/kg (250mg/kg) ? "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1117, 1986.
rat LD50 oral 444mg/kg (444mg/kg) ? Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 46(12), Pg. 13, 1981.
rat LD50 unreported 1490mg/kg (1490mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: TREMOR

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)		 Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(9), Pg. 55, 1977.
rat LDLo subcutaneous 2gm/kg (2000mg/kg) PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)

BEHAVIORAL: TREMOR

BEHAVIORAL: MUSCLE WEAKNESS		 Journal of Pharmacology and Experimental Therapeutics. Vol. 49, Pg. 78, 1933.

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