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4-Amino diphenylamine;N-Phenyl-1,4-phenylenediamine cas no:101-54-2

Synonyms: VARIAMINE BLUE RT ; Variamine Blue RT Base ; 4-(Phenylamino)aniline ; 4-amino-diphenylamin ; 4-Benzenediamine,N-phenyl-1 ; Acna Black DF Base ; acnablackdfbase ; Azosalt R ; azosaltr ; Benzenediamine, N-phenyl- ; blackbasep ; C.I. 76085 ; N-Phenyl-1,41phenylenediamine; N-Phenyl-P-Phenylenediamine

Identification
Name4-Amino diphenylamine;N-Phenyl-1,4-phenylenediamine
CAS101-54-2
SynonymsVARIAMINE BLUE RT ; Variamine Blue RT Base ; 4-(Phenylamino)aniline ; 4-amino-diphenylamin ; 4-Benzenediamine,N-phenyl-1 ; Acna Black DF Base ; acnablackdfbase ; Azosalt R ; azosaltr ; Benzenediamine, N-phenyl- ; blackbasep ; C.I. 76085 ; N-Phenyl-1,41phenylenediamine; N-Phenyl-P-Phenylenediamine
EINECS(EC#)202-951-9
Molecular FormulaC12H12N2
Molecular Weight184.24
Chemical Properties
AppearanceOdorless purple-black solid or flake or dark purple chips
refractive index1.656
storage tempKeep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass9
Safety Data

Hazard Xn:Harmful;
Risk R20/22;R36/37/38;R42/43
Safety

Moderately toxic by ingestion. A severe eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
Hazard Codes: HarmfulXn,IrritantXi
Risk Statements: 22-36-43-42/43-36/37/38-20/22
R20/22:Harmful by inhalation and if swallowed. 
R22:Harmful if swallowed. 
R36:Irritating to eyes. 
R36/37/38:Irritating to eyes, respiratory system and skin. 
R42/43:May cause sensitization by inhalation and skin contact. 
R43:May cause sensitization by skin contact. 
Safety Statements: 26-36-45-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 


HS Code 29215990

Toxicity
1.    

eye-rbt 100 mg/24H SEV

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,70.
2.    

mmo-sat 150 µg/plate

    ESKHA5    Eisei Shikenjo Hokoku. Bulletin of the National Hygiene Sciences.(94)(1976),28.
3.    

orl-rat LD50:464 mg/kg

    NCILB*    Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to the National Cancer Institute by Litton Bionetics, Inc. (Bethesda, MD) NIH-NCI-E-C-72-3252 .
4.    

orl-mus LD50:244 mg/kg

    TPKVAL    Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Sciences. 8 (1966),126.

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