106-99-0|1,3-butadieneProducts Supply - Chemical intermediates Network

1,3-butadiene cas no:106-99-0

Synonyms: Butadiene,95%; Polybutadiene,phenyl terminated

Identification

Name1,3-butadiene
CAS106-99-0
SynonymsButadiene,95%; Polybutadiene,phenyl terminated
EINECS(EC#)203-450-8
Molecular FormulaC4H6
Molecular Weight54.0904

Chemical Properties

AppearanceColorless gas (compressed liquefied gas)
refractive index1.4292
storage temp0-6°C

Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)

Hazardclass2.1

Safety Data

Hazard 2.1 UN NO.
Risk R12;R45
Safety

A flammable gas. When heated to decomposition it emits acrid smoke and irritating vapors.
Hazard Codes of Butadiene (CAS NO.106-99-0):?? Highly F+,F, Toxic T,? Dangerous N
Risk Statements: 45-46-12-67-65-63-48/20-36/38-11-62-51/53?
R45: May cause cancer.?
R46: May cause heritable genetic damage.?
R12: Extremely flammable.?
R67: Vapours may cause drowsiness and dizziness.?
R65: Harmful: may cause lung damage if swallowed.?
R63: Possible risk of harm to the unborn child.?
R48: Danger of serious damage to health by prolonged exposure.?
R20: Harmful by inhalation.?
R36/38: Irritating to eyes and skin.?
R11: Highly flammable.?
R62: Risk of impaired fertility.?
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements:?53-45-62-46-36/37-26-61-33-16?
S53: Avoid exposure - obtain special instructions before use.?
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.?
S36/37: Wear suitable protective clothing and gloves.?
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.?
S33: Take precautionary measures against static discharges.?
S16: Keep away from sources of ignition.
RIDADR: UN 1010 2.1
WGK Germany: 2
RTECS:? EI9275000
F: 4.5-31: Do not heat over 50 °C;Do not puncture.?
Hazard Note:? Extremely Flammable/Carcinogen
HazardClass:? 2.1

Toxicity

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
human	TCLo	inhalation	2000ppm/7H (2000ppm)	SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS"	Journal of Industrial Hygiene and Toxicology. Vol. 26, Pg. 69, 1944.
human	TCLo	inhalation	8000ppm (8000ppm)	SENSE ORGANS AND SPECIAL SENSES: VISUAL FIELD CHANGES: EYE SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE LUNGS, THORAX, OR RESPIRATION: COUGH	Industrial Medicine. Vol. 17, Pg. 199, 1948.
mouse	LC50	inhalation	270gm/m3/2H (270000mg/m3)	?	Archives of Environmental Health. Vol. 18, Pg. 878, 1969.
mouse	LD50	oral	3210mg/kg (3210mg/kg)	?	National Toxicology Program Technical Report Series. Vol. NTP-TR-288, Pg. 1984,
rabbit	LCLo	inhalation	25pph/23M (250000ppm)	SENSE ORGANS AND SPECIAL SENSES: MYDRIASIS (PUPILLARY DILATION): EYE BEHAVIORAL: TREMOR BEHAVIORAL: MUSCLE WEAKNESS	Journal of Industrial Hygiene and Toxicology. Vol. 26, Pg. 69, 1944.
rat	LC50	inhalation	285gm/m3/4H (285000mg/m3)	BEHAVIORAL: GENERAL ANESTHETIC LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION	Russian Pharmacology and Toxicology Vol. 31, Pg. 162, 1968.
rat	LD50	oral	5480mg/kg (5480mg/kg)	?	"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 14, 1986.

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1,3-butadiene cas no:106-99-0

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