107-31-3|Methyl formateProducts Supply - Chemical intermediates Network

Methyl formate cas no:107-31-3

Synonyms: Formic acid methyl ester; Methyl methanoate; MethylformateAmeisensuremethylester

Identification

NameMethyl formate
CAS107-31-3
SynonymsFormic acid methyl ester; Methyl methanoate; MethylformateAmeisensuremethylester
EINECS(EC#)203-481-7
Molecular FormulaC2H4O2
Molecular Weight60.05

Chemical Properties

Appearancecolourless liquid
refractive index1.342-1.344
storage tempFlammables area

Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)

Hazardclass3

Safety Data

Hazard F+:Highlyflammable;Xn:Harmful;
Risk R12;R20/22;R36/37
Safety

Moderately toxic by ingestion. Inhalation of vapor can cause irritation to nasal passages and conjunctiva, optic neuritis, narcosis, retching, and death from pulmonary irritation. Industrial fatalities have occurred only with exposure to high concentrations. Flammable liquid. Very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. Explosive in the form of vapor when exposed to heat or flame. Reacts with methanol + sodium methoxide to form an explosive product. To fight fire, use alcohol foam, CO₂, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes: Highly F+;? Harmful Xn
Risk Statements:
R12 Extremely flammable.?
R20/22 Harmful by inhalation and if swallowed.?
R36/37 Irritating to eyes and respiratory system.
Safety Statements:
S9 Keep container in a well-ventilated place.?
S16 Keep away from sources of ignition - No smoking.?
S24 Avoid contact with skin.?
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S33 Take precautionary measures against static discharges.

Toxicity

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LD50	skin	> 20mL/kg (20mL/kg)	?	National Technical Information Service. Vol. OTS0556689,
mouse	LD50	oral	675mg/kg (675mg/kg)	?	National Technical Information Service. Vol. OTS0556689,
rabbit	LD50	oral	1622mg/kg (1622mg/kg)	?	Industrial Medicine and Surgery. Vol. 41, Pg. 31, 1972.
rabbit	LD50	skin	> 5gm/kg (5000mg/kg)	?	National Technical Information Service. Vol. OTS0556797,
rat	LC50	inhalation	5200mg/m3/4H (5200mg/m3)	?	National Technical Information Service. Vol. OTS0556791,
rat	LD50	oral	475mg/kg (475mg/kg)	?	National Technical Information Service. Vol. OTS0556689,
rat	LD50	skin	> 4gm/kg (4000mg/kg)	?	National Technical Information Service. Vol. OTS0556791,

supplier list

Penta Manufacturing Company: Tel:+1-973-740-2300; Address: Box 1448 Fairfield, NJ 07006-1448 United States

Jinan Laien Chemical Co., Ltd: Tel:86-543-5081965; Address: 28 Gongye Rd. South, Jinan High-tech Zone, Jinan, China

Zhejiang Realsun Chemical Industry Co.,Ltd.: Tel:+86-576-88312598 88312526 88312597 88312579 88312576; Address: Sanshan Industrial District,Jiazhi Jiaojiang,Taizhou Zhejiang

Mitsubishi Gas Chemical Company, Inc.: Tel:+81 3-3283-5000; Address: Mitsubishi Building 2-5-2 Marunouchi, Chiyoda-ku, Tokyo

Celanese Corporation: Tel:+1-972-443-4000; Address: 1601 West LBJ Freeway Dallas, Texas 75234-6034

Zhejiang Realsun Chemical Industry Co., Ltd.: Tel:+86-(576)-8312598; Address: Sanshan Industrial District, Jiaojiang, Taizhou, Zhejiang 318013,

Penta Manufacturing Co.: Tel:+1-(973)-740-2300; Address: 50 Okner Parkway, Livingston, New Jersey 07039,

Fuhong chemical Ltd: Tel:+86-(411)-82721765; Address: 68 Renmin road, dalian 116001,

Madhu Chemicals: Tel:+91-22 67412824 / +91-22 67419980; Address:

Pharmco-Aaper: Tel:+1-(203)-740-5033, 800-243-5360; Address: 58 Vale Road, Brookfield, Connecticut 06804,

Triveni Chemicals: Tel:+91-(260)-2400022, 3258683; Address: 135, Pancharatna, Char Rasta, G.I.D.C., Vapi, Gujarat 396 195,

ECEM European Chemical Marketing BV: Tel:+31 20 3128220; Address: Hogehilweg 10 (3rd floor)

IS Chemicals Co., Ltd.: Tel:82-2-533-6533; Address: South Korea

Shijiazhuang Haima Chemicals Industry Co.,Ltd: Tel:86-311-85510837; Address: No.166 Yuhua West Road,Shijiazhuang

Shanghai Daishang Chemical Co., Ltd: Tel:+86-(21)-6260 3297; Address: Room 1102-1103, YinCheng Mansion, 3620 ZhongShan North Road, Shanghai 200063,

Methyl formate cas no:107-31-3

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