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Methyl formate cas no:107-31-3

Synonyms: Formic acid methyl ester; Methyl methanoate; MethylformateAmeisensuremethylester

Identification
NameMethyl formate
CAS107-31-3
SynonymsFormic acid methyl ester; Methyl methanoate; MethylformateAmeisensuremethylester
EINECS(EC#)203-481-7
Molecular FormulaC2H4O2
Molecular Weight60.05
Chemical Properties
Appearancecolourless liquid
refractive index1.342-1.344
storage tempFlammables area
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass3
Safety Data

Hazard F+:Highlyflammable;Xn:Harmful;
Risk R12;R20/22;R36/37
Safety

Moderately toxic by ingestion. Inhalation of vapor can cause irritation to nasal passages and conjunctiva, optic neuritis, narcosis, retching, and death from pulmonary irritation. Industrial fatalities have occurred only with exposure to high concentrations. Flammable liquid. Very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. Explosive in the form of vapor when exposed to heat or flame. Reacts with methanol + sodium methoxide to form an explosive product. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes:HighlyF+;?HarmfulXn
Risk Statements:
R12 Extremely flammable.?
R20/22 Harmful by inhalation and if swallowed.?
R36/37 Irritating to eyes and respiratory system.
Safety Statements:
S9 Keep container in a well-ventilated place.?
S16 Keep away from sources of ignition - No smoking.?
S24 Avoid contact with skin.?
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S33 Take precautionary measures against static discharges.


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 skin > 20mL/kg (20mL/kg) ? National Technical Information Service. Vol. OTS0556689,
mouse LD50 oral 675mg/kg (675mg/kg) ? National Technical Information Service. Vol. OTS0556689,
rabbit LD50 oral 1622mg/kg (1622mg/kg) ? Industrial Medicine and Surgery. Vol. 41, Pg. 31, 1972.
rabbit LD50 skin > 5gm/kg (5000mg/kg) ? National Technical Information Service. Vol. OTS0556797,
rat LC50 inhalation 5200mg/m3/4H (5200mg/m3) ? National Technical Information Service. Vol. OTS0556791,
rat LD50 oral 475mg/kg (475mg/kg) ? National Technical Information Service. Vol. OTS0556689,
rat LD50 skin > 4gm/kg (4000mg/kg) ? National Technical Information Service. Vol. OTS0556791,

supplier list

Penta Manufacturing Company
Tel:+1-973-740-2300
Address: Box 1448 Fairfield, NJ 07006-1448 United States
Qingdao Lambert Holdings Co., Ltd.
Tel:+86-(532)-80987221
Address: A508,Zhuoting Plaza,No.666,Jiangshan South Rd,Qingdao Development Zone, Qingdao, Shandong 266500,
Hebei Meida Chemicals Co., Ltd.
Tel:+86-(311)-87035158
Address: Huahai Universal Plaza , Xinhua Road, Shijiazhuang, Hebei 050000,
Foam Enterprises, LLC
Tel:+1-(763)-559-9390
Address: 13630 Watertower Circle, Minneapolis, Minnesota 55441,
Feicheng Boyuan Fine Chemicals Co., Ltd.
Tel:
Address:
Linshu Huasheng Chemical Co.,Ltd
Tel:0086-539-6462789
Address: Jiaolong town, Linshu, Shandong
Shijiazhuang Haima Chemicals Industry Co.,Ltd
Tel:86-311-85510837
Address: No.166 Yuhua West Road,Shijiazhuang
Shanghai Daishang Chemical Co., Ltd
Tel:+86-(21)-6260 3297
Address: Room 1102-1103, YinCheng Mansion, 3620 ZhongShan North Road, Shanghai 200063,
Shanghai Hope Chem Co., Ltd.
Tel:86-21-61723543
Address: Room508, Building1, No.88 CaiLun Road Zhangjiang H
Shijiazhuang Sdyano Fine Chemical Co., Ltd
Tel:86-311-80800737
Address: Room 37-2-2501, Yiyuan Dong Gang Jianshe Nan Stree
AOPHARM
Tel:86-311-66600578
Address: C-2103 Wonder Business Square, 15 Yuhua West Rd.
Boc Sciences
Tel:1-631-5046093
Address: 45-16 Ramsey Road Shirley, NY 11967, USA
Boc Sciences
Tel:1-631-5046093
Address: 45-16 Ramsey Road, Shirley, NY 11967, USA
China Huanyu Chemical Industrial Co.,Ltd
Tel:86-310-6034055
Address: Maoyi Road,Hanshan District,Handan
Win-Win chemical Co.Ltd
Tel:86-577-64498589
Address: Wenzhou china

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