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Methyl formate cas no:107-31-3

Synonyms: Formic acid methyl ester; Methyl methanoate; MethylformateAmeisensuremethylester

Identification
NameMethyl formate
CAS107-31-3
SynonymsFormic acid methyl ester; Methyl methanoate; MethylformateAmeisensuremethylester
EINECS(EC#)203-481-7
Molecular FormulaC2H4O2
Molecular Weight60.05
Chemical Properties
Appearancecolourless liquid
refractive index1.342-1.344
storage tempFlammables area
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass3
Safety Data

Hazard F+:Highlyflammable;Xn:Harmful;
Risk R12;R20/22;R36/37
Safety

Moderately toxic by ingestion. Inhalation of vapor can cause irritation to nasal passages and conjunctiva, optic neuritis, narcosis, retching, and death from pulmonary irritation. Industrial fatalities have occurred only with exposure to high concentrations. Flammable liquid. Very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. Explosive in the form of vapor when exposed to heat or flame. Reacts with methanol + sodium methoxide to form an explosive product. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes:HighlyF+;?HarmfulXn
Risk Statements:
R12 Extremely flammable.?
R20/22 Harmful by inhalation and if swallowed.?
R36/37 Irritating to eyes and respiratory system.
Safety Statements:
S9 Keep container in a well-ventilated place.?
S16 Keep away from sources of ignition - No smoking.?
S24 Avoid contact with skin.?
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S33 Take precautionary measures against static discharges.


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 skin > 20mL/kg (20mL/kg) ? National Technical Information Service. Vol. OTS0556689,
mouse LD50 oral 675mg/kg (675mg/kg) ? National Technical Information Service. Vol. OTS0556689,
rabbit LD50 oral 1622mg/kg (1622mg/kg) ? Industrial Medicine and Surgery. Vol. 41, Pg. 31, 1972.
rabbit LD50 skin > 5gm/kg (5000mg/kg) ? National Technical Information Service. Vol. OTS0556797,
rat LC50 inhalation 5200mg/m3/4H (5200mg/m3) ? National Technical Information Service. Vol. OTS0556791,
rat LD50 oral 475mg/kg (475mg/kg) ? National Technical Information Service. Vol. OTS0556689,
rat LD50 skin > 4gm/kg (4000mg/kg) ? National Technical Information Service. Vol. OTS0556791,

supplier list

Penta Manufacturing Company
Tel:+1-973-740-2300
Address: Box 1448 Fairfield, NJ 07006-1448 United States
Jinan Laien Chemical Co., Ltd
Tel:86-543-5081965
Address: 28 Gongye Rd. South, Jinan High-tech Zone, Jinan, China
Zhejiang Realsun Chemical Industry Co.,Ltd.
Tel:+86-576-88312598 88312526 88312597 88312579 88312576
Address: Sanshan Industrial District,Jiazhi Jiaojiang,Taizhou Zhejiang
Mitsubishi Gas Chemical Company, Inc.
Tel:+81 3-3283-5000
Address: Mitsubishi Building 2-5-2 Marunouchi, Chiyoda-ku, Tokyo
Celanese Corporation
Tel:+1-972-443-4000
Address: 1601 West LBJ Freeway Dallas, Texas 75234-6034
Zhejiang Realsun Chemical Industry Co., Ltd.
Tel:+86-(576)-8312598
Address: Sanshan Industrial District, Jiaojiang, Taizhou, Zhejiang 318013,
Penta Manufacturing Co.
Tel:+1-(973)-740-2300
Address: 50 Okner Parkway, Livingston, New Jersey 07039,
Fuhong chemical Ltd
Tel:+86-(411)-82721765
Address: 68 Renmin road, dalian 116001,
Madhu Chemicals
Tel:+91-22 67412824 / +91-22 67419980
Address:
Pharmco-Aaper
Tel:+1-(203)-740-5033, 800-243-5360
Address: 58 Vale Road, Brookfield, Connecticut 06804,
Triveni Chemicals
Tel:+91-(260)-2400022, 3258683
Address: 135, Pancharatna, Char Rasta, G.I.D.C., Vapi, Gujarat 396 195,
ECEM European Chemical Marketing BV
Tel:+31 20 3128220
Address: Hogehilweg 10 (3rd floor)
IS Chemicals Co., Ltd.
Tel:82-2-533-6533
Address: South Korea
Shijiazhuang Haima Chemicals Industry Co.,Ltd
Tel:86-311-85510837
Address: No.166 Yuhua West Road,Shijiazhuang
Shanghai Daishang Chemical Co., Ltd
Tel:+86-(21)-6260 3297
Address: Room 1102-1103, YinCheng Mansion, 3620 ZhongShan North Road, Shanghai 200063,

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