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Diisobutylaluminum hydride cas no:1191-15-7

Synonyms: DIBAL-H; Diisobutylaluminium hydride; Di-i-butylaluminum hydride; Diibutylaluminumhydrideinhexanecolorlessliq; DIBAH~DIBAL-H

Identification
NameDiisobutylaluminum hydride
CAS1191-15-7
SynonymsDIBAL-H; Diisobutylaluminium hydride; Di-i-butylaluminum hydride; Diibutylaluminumhydrideinhexanecolorlessliq; DIBAH~DIBAL-H
EINECS(EC#)214-729-9
Molecular FormulaC8H19Al
Molecular Weight142.22
Chemical Properties
AppearanceColorless liquid.
storage temp2-8°C
Sensitive Air Sensitive/Heat Sensitive
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass4.3
Safety Data

Hazard F:Flammable;C:Corrosive;
Risk R11;R14/15;R35;R48/20;R63;R65;R67
Safety

Mildly toxic by inhalation. Dangerous fire hazard; ignites spontaneously in air. To fight fire, do not use water, foam, or halogenated extinguishing agents. See also HYDRIDES and ALUMINUM COMPOUNDS.
 

Hazard Codes: F,T,C,N
Risk Statements:
11:  Highly Flammable
14:  Reacts violently with water
15:  Contact with water liberates extremely flammable gases
17:  Spontaneously flammable in air
19:  May form explosive peroxides
20:  Harmful by inhalation
21:  Harmful in contact with skin
22:  Harmful if swallowed 
23:  Toxic by inhalation
24:  Toxic in contact with skin
25:  Toxic if swallowed
34:  Causes burns
35:  Causes severe burns
40:  Limited evidence of a carcinogenic effect
48:  Danger of serious damage to health by prolonged exposure
49:  May cause cancer by inhalation
50:  Very Toxic to aquatic organisms
51:  Toxic to aquatic organisms
53:  May cause long-term adverse effects in the aquatic environment
60:  May impair fertility
63:  Possible risk of harm to the unborn child
65:  Harmful: May cause lung damage if swallowed
Safety Statements:
16:  Keep away from sources of ignition - No smoking
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27:  Take off immediately all contaminated clothing
29:  Do not empty into drains
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
39:  Wear eye/face protection
43:  In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
61:  Avoid release to the environment. Refer to special instructions safety data sheet
62:  If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label


Toxicity
1.    

ihl-gpg LCLo:70 g/m3/1H

    MELAAD    Medicina del Lavoro. Industrial Medicine. 57 (1966),188.

Toxicological properties of Diisobutylaluminium hydride (1191-15-7) have not been fully investigated.You can see actual entry in RTECS for complete information.

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Akzo Nobel Chemicals
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Shanghai Hanhong Chemical Co., Ltd.
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YiPeng Chemical
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Tosoh Finechem Corporation
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