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Manganese, tricarbonyl(h5-2,4-cyclopentadien-1-yl)- cas no:12079-65-1

Synonyms: Cyclopentadienylmanganesetricarbonyl (6CI);Manganese, tricarbonyl-p-cyclopentadienyl- (8CI);Cyclopentadienyl-p-tricarbonylmanganese;Cyclopentadienyltricarbonylmanganese;Cymantrene;Manganesecyclopentadienyltricarbonyl;Tricarbonyl(h5-cyclopentadienyl)manganese;Tricarbonyl-p-cyclopentadienylmanganese;Tricarbonylcyclopentadienylmanganese;h5-Cyclopentadienylmanganese tricarbonyl;p-Cyclopentadienylmanganesetricarbonyl;

Identification
NameManganese, tricarbonyl(h5-2,4-cyclopentadien-1-yl)-
CAS12079-65-1
SynonymsCyclopentadienylmanganesetricarbonyl (6CI);Manganese, tricarbonyl-p-cyclopentadienyl- (8CI);Cyclopentadienyl-p-tricarbonylmanganese;Cyclopentadienyltricarbonylmanganese;Cymantrene;Manganesecyclopentadienyltricarbonyl;Tricarbonyl(h5-cyclopentadienyl)manganese;Tricarbonyl-p-cyclopentadienylmanganese;Tricarbonylcyclopentadienylmanganese;h5-Cyclopentadienylmanganese tricarbonyl;p-Cyclopentadienylmanganesetricarbonyl;
EINECS(EC#)235-142-4
Molecular FormulaC8H5MnO3
Molecular Weight204.0615
Chemical Properties
Appearanceyellow crystals or crystalline chunks
Sensitive Air Sensitive
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1
Safety Data

Hazard Toxic material absorbed by skin. TLV: 0.1 ppm(Mn).
Risk R28
Safety

A poison by ingestion, inhalation, intraperitoneal, and intravenous routes. A mild narcotic which can damage kidneys. When heated to decomposition it emits acrid smoke and irritating fumes. See also MANGANESE COMPOUNDS and CARBON MONOXIDE.
Safety Information of Cyclopentadienylmanganese tricarbonyl (CAS NO.12079-65-1):
Hazard Codes: T+
Risk Statements: 28 
28:  Very Toxic if swallowed
Safety Statements: 28-36/37-45
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
36:  Wear suitable protective clothing  
37:  Wear suitable gloves 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 710ug/kg (0.71mg/kg)   U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#11285,
mouse LD50 oral 150mg/kg (150mg/kg) BRAIN AND COVERINGS: "CHANGES IN CIRCULATION (HEMORRHAGE, THROMBOSIS, ETC.)"

AUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETIC

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(4), Pg. 29, 1963.
rat LCLo inhalation 120mg/m3/2H (120mg/m3) VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION

BLOOD: HEMORRHAGE

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Hygiene and Sanitation Vol. 30(4-6), Pg. 40, 1965.
rat LD50 intraperitoneal 14mg/kg (14mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA
Toxicology. Vol. 34, Pg. 341, 1985.
rat LD50 oral 22mg/kg (22mg/kg)   Toxicology. Vol. 34, Pg. 341, 1985.

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