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Diphenylamine cas no:122-39-4

Synonyms: Diphenylamine(8CI);Anilinobenzene;Benzene, (phenylamino)-;DBA;DFA;DPA;N,N-Diphenylamine;N-Phenylaniline;N-Phenylbenzenamine;NSC 215210;Naugalube 428L;No-Scald;Benzenamine,N-phenyl-;

Identification
NameDiphenylamine
CAS122-39-4
SynonymsDiphenylamine(8CI);Anilinobenzene;Benzene, (phenylamino)-;DBA;DFA;DPA;N,N-Diphenylamine;N-Phenylaniline;N-Phenylbenzenamine;NSC 215210;Naugalube 428L;No-Scald;Benzenamine,N-phenyl-;
EINECS(EC#)204-539-4
Molecular FormulaC12H11N
Molecular Weight169.2224
Chemical Properties
Appearancewhite crystals or powder
refractive index1.634
storage temp0-6°C
Sensitive Air & Light Sensitive
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1
Safety Data

Hazard T:Toxic
Risk R23/24/25;R33;R50/53
Safety

Hazard Codes:?ToxicT,?DangerousN,?FlammableF
Risk Statements: 23/24/25-33-50/53-52/53-39/23/24/25-11?
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.?
R33:Danger of cumulative effects.?
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.?
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.?
R39:Danger of very serious irreversible effects.?
R11:Highly flammable.
Safety Statements: 28-36/37-45-60-61-28A-16-7?
S28:After contact with skin, wash immediately with plenty of soap-suds.?
S36/37:Wear suitable protective clothing and gloves.?
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S60:This material and its container must be disposed of as hazardous waste.?
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.?
S16:Keep away from sources of ignition.?
S7:Keep container tightly closed.
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
RTECS: JJ7800000
F: 8-10-23
HazardClass: 6.1
PackingGroup: III
Poison by ingestion. Experimental teratogenic effects. Action similar to aniline but less severe. Combustible when exposed to heat or flame. Can react violently with hexachloromelamine or trichloromelamine. Can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits highly toxic fumes of NOx. See also ANILINE, AMINES, and AROMATIC AMINES.


Toxicity
1. ???

orl-rat LD50:2?g/kg

??? GISAAA ?? Gigiena i Sanitariya. 41 (5)(1976),21.
2. ???

orl-mus LD50:1750?mg/kg

??? GISAAA ?? Gigiena i Sanitariya. 41 (5)(1976),21.
3. ???

orl-gpg LD50:300?mg/kg

??? FMCHA2 ?? Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.:?)1983,C85.

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