Manganese,[N-[2-[(dithiocarboxy)amino]ethyl]carbamodithioato(2-)-kS,kS']- cas no:12427-38-2

NameManganese,[N-[2-[(dithiocarboxy)amino]ethyl]carbamodithioato(2-)-kS,kS']-
CAS12427-38-2
SynonymsManganese,[[1,2-ethanediylbis[carbamodithioato]](2-)]-;Manganese, [[2-[(dithiocarboxy)amino]ethyl]carbamodithioato(2-)-kS,kS']- (9CI);Manganese, [ethylenebis[dithiocarbamato]]-(8CI);1,2-Ethylenediylbis(carbamodithioato)manganese;AAmangan;Agroxflowable;Carbamodithioic acid, 1,2-ethanediylbis-, manganese(2+) salt (1:1);Dithane M 22;Ethylenebis[dithiocarbamic acid] manganous salt;Graneor;Maneb;Maneb 80;Manebgan;Manesan;Manganousethylenebis[dithiocarbamate];Manzate;NM Drill Box;Nereb;Plantifog 160M;Polyram M;Saneb M 22;Trimangol;Trimangol 80;Tritogol M;ZZ-Maneb Col;
EINECS(EC#)235-654-8
Molecular FormulaC₄H₆MnN₂S₄
Molecular Weight265.301889

AppearanceYELLOW POWDER OR CRYSTALS.
storage temp0-6°C

Hazardclass4.2

Hazard Xi
Safety

Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. A fungicide. May ignite spontaneously in air. When heated to decomposition it emits highly toxic fumes of NO_x and SO_x. See also MANGANESE COMPOUNDS and CARBAMATES.
Hazard Codes:
Xi: Irritant
Risk Statements about Manganese(ii) ethylenebis(dithiocar-bamate) (12427-38-2):
R37 Irritating to respiratory system.
R43 May cause sensitization by skin contact.
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
Safety Statements about Manganese(ii) ethylenebis(dithiocar-bamate) (12427-38-2):
S8 Keep container dry.
S22 Do not breathe dust.
S46 If swallowed, seek medical advice immediately and show this container or label.
S24/25: Avoid contact with skin and eyes.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
Attention:
1. Storage: Keep in well-ventilated area. Keep away from fire and sparks. Do not allow wetting or overheating, which could cause deterioration of fungicidal effectiveness and may generate flammable vapors.
2. Handling: All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
3. Health Hazard: Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.

1.		mmo-omi 1000 ppm		MMAPAP    Mycopathologia et Mycologia Applicata. 50 (1973),233.
2.		mmo-smc 5 ppm		RSTUDV    Rivista di Scienza e Technologia degli Alimenti e di Nutrizione Umana. Review of Science and Technology of Food and Human Nutrition. 6 (1976),161.
3.		cyt-ham:lng 31 mg/L		GMCRDC    Gann Monograph on Cancer Research. 27 (1981),95.
4.		orl-rat TDLo:1420 mg/kg (11D preg):TER		TJADAB    Teratology, A Journal of Abnormal Development. 14 (1976),171.
5.		orl-rat TDLo:62,980 mg/kg/94W-I:CAR		VPITAR    Voprosy Pitaniya. Problems of Nutrition. 29 (1970),71.
6.		imp-rat TDLo:50 mg/kg:ETA		VPITAR    Voprosy Pitaniya. Problems of Nutrition. 29 (1970),71.
7.		unr-rat LD50:3 g/kg		EQSFAP    Environmental Quality and Safety. 3 (1975),618.
8.		orl-rat LD50:3 g/kg		GISAAA    Gigiena i Sanitariya. 36 (5)(1971),22.
9.		orl-mus LD50:2600 mg/kg		GISAAA    Gigiena i Sanitariya. 36 (5)(1971),22.
10.		orl-gpg LDLo:6400 mg/kg		PCOC**    Pesticide Chemicals Official Compendium ,Association of the Am