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Molybdenum(VI) oxide cas no:1313-27-5

Synonyms: Molybdenum anhydride; Molybdic oxide

Identification
NameMolybdenum(VI) oxide
CAS1313-27-5
SynonymsMolybdenum anhydride; Molybdic oxide
EINECS(EC#)215-204-7
Molecular FormulaMoO3
Molecular Weight143.94
Chemical Properties
Appearancepale yellowish-green powder
Safety Data

Hazard Xn:Harmful;
Risk R36/37;R48/20/22
Safety

Poison by ingestion, subcutaneous, and intraperitoneal routes. Human systemic effects by inhalation: pulmonary fibrosis and cough. Questionable carcinogen with experimental neoplastigenic data. A powerful irritant. Explodes on contact with molten magnesium. Violent reaction with interhalogens (e.g., bromine pentafluoride, chlorine trifluoride). Incandescent reaction with hot sodium, potassium, or lithium. When heated to decomposition it emits toxic fumes of Mo. See also MOLYBDENUM COMPOUNDS.
Hazard Codes: Xn,Xi
Risk Statements: 36/37-48/20/22
20: ?Harmful by inhalation
22: ?Harmful if swallowed
36: ?Irritating to the eyes
37: ?Irritating to the respiratory system
48: ?Danger of serious damage to health by prolonged exposure
Safety Statements: 22-23-25
22: ?Do not breathe dust
23: ?Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)?
25: ?Avoid contact with eyes


Toxicity
Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD75 intraperitoneal 400mg/kg (400mg/kg) ? Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
man TCLo inhalation 6mg/m3/4Y (6mg/m3) LUNGS, THORAX, OR RESPIRATION: "FIBROSIS, FOCAL (PNEUMOCONIOSIS)"

LUNGS, THORAX, OR RESPIRATION: COUGH
National Technical Information Service. Vol. AEC-TR-6710,
mouse LD50 intraperitoneal 141mg/kg (141mg/kg) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 9(6), Pg. 40, 1965.
mouse LD50 subcutaneous 94mg/kg (94mg/kg) ? Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva. Journal of the D.I. Mendeleeva All-Union Chemical Society. Vol. 19, Pg. 186, 1974.
rat LC50 inhalation > 5840mg/m3/4H (5840mg/m3) ? Cyprus Copper Company. Vol. 18JUN1991,
rat LD50 oral 2689mg/kg (2689mg/kg) ? Cyprus Copper Company. Vol. 18JUN1991,
rat LD50 skin > 2gm/kg (2000mg/kg) ? Cyprus Copper Company. Vol. 18JUN1991,

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