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Benzenamine,4,4'-thiobis- cas no:139-65-1

Synonyms: Aniline,4,4'-thiodi- (6CI,8CI);4,4'-Diaminodiphenyl sulfide;4,4'-Diaminophenylsulfide;4,4'-Thiobis[aniline];4,4'-Thiodianiline;4-(Aminophenylthio)phenylamine;BAPS;Bis(4-aminophenyl) sulfide;Di(p-aminophenyl) sulfide;NSC 6191;Thioaniline;Thiodi-p-phenylenediamine;p,p-Thiodianiline;p,p'-Diaminodiphenyl sulfide;

Identification
NameBenzenamine,4,4'-thiobis-
CAS139-65-1
SynonymsAniline,4,4'-thiodi- (6CI,8CI);4,4'-Diaminodiphenyl sulfide;4,4'-Diaminophenylsulfide;4,4'-Thiobis[aniline];4,4'-Thiodianiline;4-(Aminophenylthio)phenylamine;BAPS;Bis(4-aminophenyl) sulfide;Di(p-aminophenyl) sulfide;NSC 6191;Thioaniline;Thiodi-p-phenylenediamine;p,p-Thiodianiline;p,p'-Diaminodiphenyl sulfide;
EINECS(EC#)205-370-9
Molecular FormulaC12H12N2S
Molecular Weight216.32
Chemical Properties
Appearancebrown to brown-violet powder or needles
refractive index1.707
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
HazardclassIRRITANT
Safety Data

Hazard T: Toxic;N: Dangerous for the environment;
Risk R45;R22;R51/53
Safety

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intravenous route. Moderately toxic by ingestion. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also SULFIDES.
Safety information of 4,4'-Sulfanediyldianiline (139-65-1):
Hazard Codes  T,N
Risk Statements 
45  May cause cancer
22  Harmful if swallowed
51/53  Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements 
53  Avoid exposure - obtain special instruction before use
45  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
61  Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  BY9625000
F  8-10-21


Toxicity
1.    

mmo-sat 10 µg/plate

    MUREAV    Mutation Research. 67 (1979),123.
2.    

mma-sat 10 µg/plate

    MUREAV    Mutation Research. 67 (1979),123.
3.    

orl-rat TDLo:3600 mg/kg/27D-I:CAR

    CNREA8    Cancer Research. 28 (1968),924.
4.    

orl-rat LD50:1100 mg/kg

    MarJV#    Personal Communication from Josef V. Marhold, VUOS, 539-18, Pardubice, Czechoslovakia, to the Editor of RTECS, Cincinnati, OH, March 29, 1977 29MAR77 .
5.    

orl-mus LD50:620 mg/kg

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,43.
6.    

ivn-mus LD50:180 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#01564 .

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