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Tert-butyl methyl ether cas no:1634-04-4

Synonyms: 2-methoxy-2-methylpropane; methyl t-butyl ether; Methyl Tertiary Butyl Ether; Methyl Tertiary Butyl Ether (MTBE); MTBE; Methyl tert-Butyl Ether;

Identification
NameTert-butyl methyl ether
CAS1634-04-4
Synonyms2-methoxy-2-methylpropane; methyl t-butyl ether; Methyl Tertiary Butyl Ether; Methyl Tertiary Butyl Ether (MTBE); MTBE; Methyl tert-Butyl Ether;
EINECS(EC#)216-653-1
Molecular FormulaC5H12O
Molecular Weight88.15
Chemical Properties
Appearanceclear liquid
refractive index1.3675-1.3695
storage temp?20°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass3
Safety Data

Hazard F:Flammable
Risk R11;R38
Safety

Hazard Codes?of tert-Butyl methyl ether (CAS NO.1634-04-4):?HarmfulXn,FlammableF,IrritantXiToxicT
Risk Statements: 36/37/38-40-11-39-23/24/25
R36/37/38: Irritating to eyes, respiratory system and skin.?
R40: Limited evidence of a carcinogenic effect.?
R11: Highly flammable.?
R39: Danger of very serious irreversible effects.?
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 9-16-24-45-36/37?
S9: Keep container in a well-ventilated place.?
S16: Keep away from sources of ignition.?
S24: Avoid contact with skin.?
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S36/37: Wear suitable protective clothing and gloves.
RIDADR: UN 2398 3/PG 2
WGK Germany: 3
RTECS: KN5250000
F: 3-10
HazardClass: 3
PackingGroup: II
Hazardous Substances Data: 1634-04-4(Hazardous Substances Data)
Poison by intravenous route. Slightly toxic by ingestion and inhalation. Flammable when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 141gm/m3/15M (141000mg/m3) BEHAVIORAL: GENERAL ANESTHETIC Anesthesiology. Vol. 11, Pg. 455, 1950.
mouse LD50 intraperitoneal 1700uL/kg (1.7mL/kg) ? Zhonghua Yixue Zazhi. Chinese Medical Journal. Vol. 70, Pg. 172, 1990.
mouse LD50 oral 5960uL/kg (5.96mL/kg) ? Zhonghua Yixue Zazhi. Chinese Medical Journal. Vol. 70, Pg. 172, 1990.
rat LC50 inhalation 23576ppm/4H (23576ppm) ? National Technical Information Service. Vol. PB87-174603,
rat LD intraperitoneal > 148mg/kg (148mg/kg) ? Journal of Surgical Research. Vol. 53, Pg. 572, 1992.
rat LD50 oral 4gm/kg (4000mg/kg) ? National Technical Information Service. Vol. PB87-174603,
rat LDLo intravenous 148mg/kg (148mg/kg) ? Journal of Surgical Research. Vol. 53, Pg. 572, 1992.

supplier list

Seidler Chemical Co., Inc.
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Lyondell Chemical
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Lyondell Chemical Company
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Jilian (Jilin) Pertrochemicals Ltd.
Tel:+86-(432)-3903651
Address: No. 9, Longtan Street, Longtan District, Jilin City, Jilin Province 132021,
Applichem GmbH
Tel:+49-(6151)-93570
Address: 4, Ottoweg, Darmstadt 64291,
Bharat Petroleum Corporation Limited
Tel:+91-(22)-22189172
Address: Maker Towers E & F,12th Floor, Cuffe Parade, Mumbai, Maharashtra 400005,
Mitsubishi Chemical Corporation
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Address: 14-1 Shiba 4-chome, Minato-ku, Tokyo 108-0014,
Saudi Basic Industries Corporation (SABIC)
Tel:+966-(1)-225 8000
Address: Post Box 5101, Riyadh 11422,
National Methanol Co.
Tel:+966-(3)-340-5500
Address: P.O. Box 10003, Jubail Industrial City 31961,
Ashland Inc.
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Address: 50 E. River Centre Blvd., Covington, Kentucky 41101,
Amoco Chemical Co.
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Address: MC 4106, Department 1398, 200 East Randolph Drive, Chicago, Illinois 60601,
American Agip Co., Inc.
Tel:+1-(212)-887-0250
Address: 666 Fifth Avenue - 5th Floor, New York 10103,
Chevron Phillips Chemical Company LLC
Tel:+1-(832)-813-4100, 800-231-1212
Address: 10001 Six Pines Drive, The Woodlands, Texas 77380,
EMD Chemicals Inc.
Tel:+1-(856)-423-6300
Address: 480 S. Democrat Road, Gibbstown, New Jersey 08027,
Huntsman Corporation
Tel:+1-(801)-584-5700
Address: 500 Huntsman Way, Salt Lake City, Utah 84108,

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