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Tert-butyl methyl ether cas no:1634-04-4

Synonyms: 2-methoxy-2-methylpropane; methyl t-butyl ether; Methyl Tertiary Butyl Ether; Methyl Tertiary Butyl Ether (MTBE); MTBE; Methyl tert-Butyl Ether;

Identification
NameTert-butyl methyl ether
CAS1634-04-4
Synonyms2-methoxy-2-methylpropane; methyl t-butyl ether; Methyl Tertiary Butyl Ether; Methyl Tertiary Butyl Ether (MTBE); MTBE; Methyl tert-Butyl Ether;
EINECS(EC#)216-653-1
Molecular FormulaC5H12O
Molecular Weight88.15
Chemical Properties
Appearanceclear liquid
refractive index1.3675-1.3695
storage temp?20°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass3
Safety Data

Hazard F:Flammable
Risk R11;R38
Safety

Hazard Codes?of tert-Butyl methyl ether (CAS NO.1634-04-4):?HarmfulXn,FlammableF,IrritantXiToxicT
Risk Statements: 36/37/38-40-11-39-23/24/25
R36/37/38: Irritating to eyes, respiratory system and skin.?
R40: Limited evidence of a carcinogenic effect.?
R11: Highly flammable.?
R39: Danger of very serious irreversible effects.?
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 9-16-24-45-36/37?
S9: Keep container in a well-ventilated place.?
S16: Keep away from sources of ignition.?
S24: Avoid contact with skin.?
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S36/37: Wear suitable protective clothing and gloves.
RIDADR: UN 2398 3/PG 2
WGK Germany: 3
RTECS: KN5250000
F: 3-10
HazardClass: 3
PackingGroup: II
Hazardous Substances Data: 1634-04-4(Hazardous Substances Data)
Poison by intravenous route. Slightly toxic by ingestion and inhalation. Flammable when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 141gm/m3/15M (141000mg/m3) BEHAVIORAL: GENERAL ANESTHETIC Anesthesiology. Vol. 11, Pg. 455, 1950.
mouse LD50 intraperitoneal 1700uL/kg (1.7mL/kg) ? Zhonghua Yixue Zazhi. Chinese Medical Journal. Vol. 70, Pg. 172, 1990.
mouse LD50 oral 5960uL/kg (5.96mL/kg) ? Zhonghua Yixue Zazhi. Chinese Medical Journal. Vol. 70, Pg. 172, 1990.
rat LC50 inhalation 23576ppm/4H (23576ppm) ? National Technical Information Service. Vol. PB87-174603,
rat LD intraperitoneal > 148mg/kg (148mg/kg) ? Journal of Surgical Research. Vol. 53, Pg. 572, 1992.
rat LD50 oral 4gm/kg (4000mg/kg) ? National Technical Information Service. Vol. PB87-174603,
rat LDLo intravenous 148mg/kg (148mg/kg) ? Journal of Surgical Research. Vol. 53, Pg. 572, 1992.

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