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Lithium tri-tert-butoxyaluminohydride cas no:17476-04-9

Synonyms: lithium aluminum-tri-tert-butoxyhydride; aluminium lithium tri-tert-butoxide hydride; Lithiumaluminiumtritertbutoxyhydride; Lithium tri-t-butoxyaluminohydride

Identification
NameLithium tri-tert-butoxyaluminohydride
CAS17476-04-9
Synonymslithium aluminum-tri-tert-butoxyhydride; aluminium lithium tri-tert-butoxide hydride; Lithiumaluminiumtritertbutoxyhydride; Lithium tri-t-butoxyaluminohydride
EINECS(EC#)241-490-8
Molecular FormulaC12H28AlLiO3
Molecular Weight254.27
Chemical Properties
Appearancewhite powder
storage temp2-8°C
Sensitive Air & Moisture Sensitive
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass4.3
Safety Data

Hazard F:Flammable;C:Corrosive;
Risk R11;R14/15;R19;R35
Safety

Poison by intravenous route. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALUMINUM and LITHIUM COMPOUNDS.
Hazard Codes:
F: Flammable
C: Corrosive
Risk Statements about Lithium aluminum tri-tert-butoxyhydride (17476-04-9):
R11 Highly flammable. 
R14/15 Reacts violently with water liberating extremely flammable gases. 
R19 May form explosive peroxides. 
R35 Causes severe burns
Safety Statements about Lithium aluminum tri-tert-butoxyhydride (17476-04-9):
S6A Keep under nitrogen. 
S16 Keep away from sources of ignition - No smoking. 
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 
S43B In case of fire, use fire-fighting equipment on basis of sodium chloride, sodium bicarbonate (never use water). 
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible
Attention:
1. Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container
2. Handling: Do not allow water to get into the container because of violent reaction. Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not allow contact with water. Use only in a chemical fume hood


Toxicity
1.    

ivn-mus LD50:32 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#00620 .

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