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Phosphonic acid,dibutyl ester cas no:1809-19-4

Synonyms: Butylphosphite ((C4H9O)2(HO)P) (6CI,7CI); Butyl alcohol, hydrogen phosphite; Butylphosphonate ((BuO)2HPO); Butyl phosphonate ((C4H9O)2HPO); DBP 1; Di-n-butylhydrogen phosphite; Di-n-butyl phosphite; Dibutoxyphosphine oxide; Dibutylhydrogen phosphite; Dibutyl phosphite; Dibutyl phosphonate; NSC 2668;Phosphorous acid, dibutyl ester

Identification
NamePhosphonic acid,dibutyl ester
CAS1809-19-4
SynonymsButylphosphite ((C4H9O)2(HO)P) (6CI,7CI); Butyl alcohol, hydrogen phosphite; Butylphosphonate ((BuO)2HPO); Butyl phosphonate ((C4H9O)2HPO); DBP 1; Di-n-butylhydrogen phosphite; Di-n-butyl phosphite; Dibutoxyphosphine oxide; Dibutylhydrogen phosphite; Dibutyl phosphite; Dibutyl phosphonate; NSC 2668;Phosphorous acid, dibutyl ester
EINECS(EC#)217-316-1
Molecular FormulaC8H19 O3 P
Molecular Weight194.21
Chemical Properties
Appearancecolorless
refractive index1.4225-1.4245
storage tempKeep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Flammables-area. Store protected from moisture.
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass8
Safety Data

Hazard Xn:Harmful;
Risk R21;R36/37/38
Safety

Moderately toxic by ingestion and skin contact. A skin and severe eye irritant. Flammable liquid when exposed to heat or flame or by chemical reaction. Many phosphites decompose to evolve PHOSPHINE when heated. Explosion Hazard: See PHOSPHINE. Can react vigorously with oxidizing materials. To fight fire, use foam, CO2, dry chemical. Dangerous; when heated to decomposition or on contact with acid or acid fumes it emits highly toxic fumes of POx.
Hazard Codes:  Xn 
Xn:  Harmful
Risk Statements:  21-37/38-40-41-36/37/38
21:  Harmful in contact with skin 
41:  Risk of serious damage to eyes 
36/37/38:  Irritating to eyes, respiratory system and skin 
37/38:  Irritating to respiratory system and skin
Safety Statements:  26-36/37/39 
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36/37/39: Wear suitable protective clothing, gloves and eye/face protection


Toxicity
1.    

skn-rbt 10 mg/24H open MLD

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 31 (1949),60.
2.    

eye-rbt 250 µg open SEV

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 31 (1949),60.
3.    

orl-rat LD50:3200 mg/kg

    ALBRW*    Albright and Wilson Inc., P.O. Box 26229, Richmond, VA 23260-6229 #OPB-3 ,1984.
4.    

skn-rbt LD50:1990 mg/kg

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 31 (1949),60.

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