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Molinate (1H-Azepine-1-carbothioic acid, hexahydro-S-ethyl ester) cas no:2212-67-1

Synonyms: Ethyl1-hexamethyleneiminecarbothiolate; Felan; Hydram; Jalan; Molinate; Ordram; R4572; S-Ethyl N,N-hexamethylenethiocarbamate; S-Ethylhexahydro-1H-azepine-1-carbothioate; S-Ethyl hexahydroazepine-1-carbothioate;SC 9908; Stauffer R 4572; Yalan; Yulan

Identification
NameMolinate (1H-Azepine-1-carbothioic acid, hexahydro-S-ethyl ester)
CAS2212-67-1
SynonymsEthyl1-hexamethyleneiminecarbothiolate; Felan; Hydram; Jalan; Molinate; Ordram; R4572; S-Ethyl N,N-hexamethylenethiocarbamate; S-Ethylhexahydro-1H-azepine-1-carbothioate; S-Ethyl hexahydroazepine-1-carbothioate;SC 9908; Stauffer R 4572; Yalan; Yulan
EINECS(EC#)218-661-0
Molecular FormulaC9H17 N O S
Molecular Weight187.302
Chemical Properties
AppearanceClear liquid with aromatic odor.
refractive index1.5092 (25 C)
storage temp0-6°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(b)
Safety Data

Hazard T,N,Xn:;
Risk R20/22
Safety

Poison by inhalation. Moderately toxic by ingestion, skin contact, and subcutaneous routes. Experimental reproductive effects. Human mutation data reported. An herbicide. When heated to decomposition it emits very toxic fumes of NOx and SOx.
 

Hazard Codes: T,N,Xn
Risk Statements:
20:  Harmful by inhalation
22:  Harmful if swallowed 
40:  Limited evidence of a carcinogenic effect
43:  May cause sensitization by skin contact
48:  Danger of serious damage to health by prolonged exposure
50:  Very Toxic to aquatic organisms
53:  May cause long-term adverse effects in the aquatic environment
63:  Possible risk of harm to the unborn child
Safety Statements:
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
46:  If swallowed, seek medical advice immediately and show this container or label
60:  This material and/or its container must be disposed of as hazardous waste
61:  Avoid release to the environment. Refer to special instructions safety data sheet


Toxicity
Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LC50 inhalation > 200mg/m3 (200mg/m3)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 35(8), Pg. 35, 1970.
mammal (species unspecified) LD50 unreported 720mg/kg (720mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(5), Pg. 29, 1980.
mouse LD50 oral 530mg/kg (530mg/kg) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE
SENSE ORGANS AND SPECIAL SENSES: CHANGES IN EXTRA-OCULAR MUSCLES: EYE
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
Vrachebnoe Delo. Medical Practice. Vol. (1), Pg. 119, 1969.
 
mouse LD50 unreported 545mg/kg (545mg/kg) SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 40(10), Pg. 104, 1975.
rabbit LD50 skin 3536mg/kg (3536mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C208, 1991.
rat LC50 inhalation 2100mg/m3/1H (2100mg/m3)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A282, Pg. 1983,
rat LD50 oral 369mg/kg (369mg/kg)   Pesticide Manual. Vol. 9, Pg. 594, 1991.
rat LD50 skin 1167mg/kg (1167mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 35(8), Pg. 35, 1970.
rat LD50 unreported 657mg/kg (657mg/kg) SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 40(10), Pg. 104,

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SHENZHEN AGRO HUNTER CO.,LTD.
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SINOCO CHEMICAL CO., LIMITED
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NINGBO AGRO-STAR INDUSTRIAL CO., LTD.
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Hangzhou J&H Chemical Co., Ltd
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Hangzhou Dayangchem Co., Ltd.
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Zhejiang Haiqiang Chemical Co.,Ltd.
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Jinan Haohua Industry Co., Ltd.
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Wuhan Haizheng Industry & Trade Development Co. Ltd
Tel:86-27-88660577
Address: 27th FL.shuian international masion Bldg.1,Heping Ave.wuhan city
Wuhan Haizheng Industry & Trade Development Co. Ltd
Tel:86-27-88660577
Address: 27th FL.shuian international masion Bldg.1,Heping Ave.wuhan city
Wuhan Haizheng Industry & Trade Development Co. Ltd
Tel:86-27-88660577
Address: 27th FL.shuian international masion Bldg.1,Heping Ave.wuhan city

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