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Phosphorodithioic acid,S-[(6-chloro-2-oxo-3(2H)-benzoxazolyl)methyl] O,O-diethyl ester cas no:2310-17-0

Synonyms: Phosphorodithioicacid, O,O-diethyl ester, S-ester with 6-chloro-3-(mercaptomethyl)-2-benzoxazolinone(7CI,8CI);3-(O,O-Diethyldithiophosphorylmethyl)-6-chlorobenzoxazolinone;6-Chloro-3-(O,O-diethyldithiophosphorylmethyl)benzoxazolone;Agria 1060;Benzophosphate;Chipman 11974;Fosalon;KB insectes;NIA 9241;O,O-DiethylS-[6-chloro-3-(mercaptomethyl)-2-benzoxazolinone]phosphorodithioate;Phosalon;RP 11974;Rubitox;S-(6-Chloro-2-oxobenzoxazolin-3-yl)methyl diethyl phosphorothiolothionate;S-[6-Chloro-3-(mercaptomethyl)-2-benzoxazolinone] O,O-diethylphosphorodithioate;Zolone Flo;Zolone PM;

Identification
NamePhosphorodithioic acid,S-[(6-chloro-2-oxo-3(2H)-benzoxazolyl)methyl] O,O-diethyl ester
CAS2310-17-0
SynonymsPhosphorodithioicacid, O,O-diethyl ester, S-ester with 6-chloro-3-(mercaptomethyl)-2-benzoxazolinone(7CI,8CI);3-(O,O-Diethyldithiophosphorylmethyl)-6-chlorobenzoxazolinone;6-Chloro-3-(O,O-diethyldithiophosphorylmethyl)benzoxazolone;Agria 1060;Benzophosphate;Chipman 11974;Fosalon;KB insectes;NIA 9241;O,O-DiethylS-[6-chloro-3-(mercaptomethyl)-2-benzoxazolinone]phosphorodithioate;Phosalon;RP 11974;Rubitox;S-(6-Chloro-2-oxobenzoxazolin-3-yl)methyl diethyl phosphorothiolothionate;S-[6-Chloro-3-(mercaptomethyl)-2-benzoxazolinone] O,O-diethylphosphorodithioate;Zolone Flo;Zolone PM;
EINECS(EC#)218-996-2
Molecular FormulaC12H15ClNO4PS2
Molecular Weight367.81
Chemical Properties
Appearancecolourless or white crystals
refractive index1.608
storage temp0-6°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(b)
Safety Data

Hazard T,N:;
Risk R21
Safety

Poison by ingestion, skin contact, and possibly other routes. A cholinesterase inhibitor. See also PARATHION. When heated to decomposition it emits very toxic fumes of Cl, NOx, POx, and SOx.
 

Hazard Codes: T,N
Risk Statements:
21:  Harmful in contact with skin
25:  Toxic if swallowed
50:  Very Toxic to aquatic organisms
53:  May cause long-term adverse effects in the aquatic environment
Safety Statements:
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
60:  This material and/or its container must be disposed of as hazardous waste
61:  Avoid release to the environment. Refer to special instructions safety data sheet


Toxicity
1.    

orl-rat LD50:85 mg/kg

    KSKZAN    Khimiya v Sel’skom Khozyaistve. Chemistry in Agriculture. 16 (2)(1978),59.
2.    

skn-rat LD50:390 mg/kg

    WRPCA2    World Review of Pest Control. 9 (1970),119.
3.    

unr-rat LD50:135 mg/kg

    30ZDA9    Chemistry of Pesticides. Melnikov, N.N.,New York, NY.: Springer-Verlag,1971,371.
4.    

orl-mus LD50:73 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 19 (9)(1975),55.
5.    

skn-rbt LD50:1000 mg/kg

    85DPAN    Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow, Berlin, Germany, Verlag Paul Parey, 1971-1976
6.    

orl-gpg LD50:150 mg/kg

    GUCHAZ    Guide to the Chemicals Used in Crop Protection 6 (1973),408.
7.    

orl-ckn LD50:661 mg/kg

    VETNAL    Veterinariya. 54 (11)(1978),75.

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