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Phosphorothioic acid,O,O-diethyl O-[2-(ethylthio)ethyl] ester cas no:298-03-3

Synonyms: Phosphorothioicacid, O,O-diethyl ester O-[2-(ethylthio)ethyl] ester (6CI); Demeton-O; Demetonthione;NSC 8928; O,O-Diethyl O-[2-(ethylthio)ethyl] phosphorothionate

Identification
NamePhosphorothioic acid,O,O-diethyl O-[2-(ethylthio)ethyl] ester
CAS298-03-3
SynonymsPhosphorothioicacid, O,O-diethyl ester O-[2-(ethylthio)ethyl] ester (6CI); Demeton-O; Demetonthione;NSC 8928; O,O-Diethyl O-[2-(ethylthio)ethyl] phosphorothionate
EINECS(EC#)206-053-8
Molecular FormulaC8H19 O3 P S2
Molecular Weight258.36
Chemical Properties
refractive index1.5
storage temp−20°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(a)
Safety Data

Hazard T+: Very toxic;N: Dangerous for the environment;
Risk 27/28-50
Safety

Poison by ingestion, skin contact, subcutaneous, and intraperitoneal routes. Human mutation data reported. An insecticide. When heated to decomposition it emits toxic fumes of POx and SOx. See also DEMETON-O + DEMETON-S and DEMETON-O-METHYL; DEMETON-O-METHYL SULFOXIDE; DEMETON-S; DEMETON-S-METHYL; DEMETON-S-METHYL-SULPHONE.
Analytical Methods: 
For occupational chemical analysis use NIOSH: Demeton, 5514.
Safety Information of Demeton-O (CAS NO.298-03-3):
Hazard Codes: T+Very,NDangerous
Risk Statements: 27/28-50 
27:  Very Toxic in contact with skin 
28:  Very Toxic if swallowed 
50:  Very Toxic to aquatic organisms 
Safety Statements: 28-36/37-45-61
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 
36:  Wear suitable protective clothing  
37:  Wear suitable gloves 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
61:  Avoid release to the environment. Refer to special instructions safety data sheet 


Toxicity
1.    

mmo-esc 200 µg/plate

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB80-133226 .
2.    

mma-esc 200 µg/plate

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB80-133226 .
3.    

dnr-bcs 5 µg/disc

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB80-133226 .
4.    

mma-smc 1000 ppm

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB80-133226 .
5.    

dns-hmn:fbr 100 mg/L

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB80-133226 .
6.    

cyt-ham-ipr 2 mg/kg

    ARTODN    Archives of Toxicology. 58 (1985),152.
7.    

orl-rat LD50:7500 µg/kg

    GUCHAZ    Guide to the Chemicals Used in Crop Protection 6 (1973),161.
8.    

scu-mus LD50:15 mg/kg

    AEPPAE    Naunyn-Schmiedebergs Archiv fuer Experimentelle Pathologie und Pharmakologie. 217 (1953),144.
9.    

skn-rbt LDLo:100&

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