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Thiocyclam hydrogen oxalate cas no:31895-22-4

Synonyms: bis(1,2,3-trithiacyclohexyldimethylammonium) oxalate

Identification
NameThiocyclam hydrogen oxalate
CAS31895-22-4
Synonymsbis(1,2,3-trithiacyclohexyldimethylammonium) oxalate
EINECS(EC#)250-859-2
Molecular FormulaC5H11NS3.C2H2O4
Molecular Weight271.37742
Chemical Properties
Appearancecolourless crystalline
storage temp0-6°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(b)
Safety Data

Hazard Xn: Harmful;N: Dangerous for the environment;
Risk R21/22
Safety

Poison by ingestion. Moderately toxic by skin contact. When heated to decomposition it emits very toxic fumes of NOx, NH3, and SOx.Safety information of Thiocyclam hydrogen oxalate (CAS NO.31895-22-4):
Hazard Codes  HarmfulXn,DangerousN
Risk Statements 
21/22 Harmful in contact with skin and if swallowed
50/53 Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements 
36/37 Wear suitable protective clothing and gloves
46 If swallowed, seek medical advice immediately and show this container or label
60 This material and/or its container must be disposed of as hazardous waste
61 Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR  2588
RTECS  YL8300000
HazardClass  6.1(b)
PackingGroup  III


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 37200mg/kg (37200mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 12, Pg. 339, 1987.
mouse LD50 oral 156mg/kg (156mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(11), Pg. 71, 1985.
mouse LD50 subcutaneous 33900mg/kg (33900mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 12, Pg. 339, 1987.
quail LD50 oral 3450ug/kg (3.45mg/kg)   Pesticide Manual. Vol. 9, Pg. 816, 1991.
rat LC50 inhalation > 4500mg/m3 (4500mg/m3)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A393, Pg. 1983,
rat LD50 intraperitoneal 22900mg/kg (22900mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 12, Pg. 339, 1987.
rat LD50 oral 195mg/kg (195mg/kg)   Khimiya v Sel'skom Khozyaistve. Chemistry in Agriculture. Vol. 16(2), Pg. 59, 1978.
rat LD50 skin 1gm/kg (1000mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C301, 1991.
rat LD50 subcutaneous 27900mg/kg (27900mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 12, Pg. 339, 1987.

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