lithium diisopropylamide cas no:4111-54-0
Synonyms: 2-Propanamine,N-(1-methylethyl)-, lithium salt (9CI); Diisopropylamine, lithium salt (8CI);Lithium, (diisopropylamino)- (7CI); (Diisopropylamino)lithium; LDA; LDA(reagent); Lithiodiisopropylamine; Lithium diisopropylamide; Lithiumdiisopropylamine; N-(1-Methylethyl)-2-propanamine lithium salt;N-Lithiodiisopropylamide
Namelithium diisopropylamide
CAS4111-54-0
Synonyms2-Propanamine,N-(1-methylethyl)-, lithium salt (9CI); Diisopropylamine, lithium salt (8CI);Lithium, (diisopropylamino)- (7CI); (Diisopropylamino)lithium; LDA; LDA(reagent); Lithiodiisopropylamine; Lithium diisopropylamide; Lithiumdiisopropylamine; N-(1-Methylethyl)-2-propanamine lithium salt;N-Lithiodiisopropylamide
EINECS(EC#)223-893-0
Molecular FormulaC6H14LiN
Molecular Weight107.12
storage temp2-8°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass4.2
Hazard F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;
Risk R11;R14;R15;R19;R35;R51/53;R65;R67
Safety
Hazard Codes:
C,
N,
F
Risk Statements: 14-17-34-67-65-51/53-35-19-15-11-50/53-14/15-10-40-23/24/25
R14 :Reacts violently with water.
R17:Spontaneously flammable in air.
R34:Causes burns.
R67:Vapours may cause drowsiness and dizziness.
R65:Harmful: may cause lung damage if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R35:Causes severe burns.
R19:May form explosive peroxides.
R15:Contact with water liberates extremely flammable gases.
R11:Highly flammable.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R14 :Reacts violently with water.
R10:Flammable.
R40:Limited evidence of a carcinogenic effect.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 26-36/37/39-43-45-60-61-62-8-16-23-33-27
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S62:If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
S8:Keep container dry.
S16:Keep away from sources of ignition.
S23:Do not breathe vapour.
S33:Take precautionary measures against static discharges.
S27:Take off immediately all contaminated clothing.
RIDADR: UN 3399 4.3/PG 2
WGK Germany of Lithium diisopropylamide (CAS NO.4111-54-0): 3