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4,4'-Bipyridinium,1,1'-dimethyl- cas no:4685-14-7

Synonyms: 1,1'-Dimethyl-4,4'-bipyridinium;1,1'-Dimethyl-4,4'-bipyridinium cation;Dimethyl viologen;Methyl viologendication;Methyl viologen ion(2+);Methyl viologen(2+);N,N'-Dimethyl-4,4'-bipyridinium;N,N'-Dimethyl-4,4'-bipyridinium dication;Paraquat dication;Paraquat ion;Spraytop-graze;Starfire;Paraquat dichloride;

Identification
Name4,4'-Bipyridinium,1,1'-dimethyl-
CAS4685-14-7
Synonyms1,1'-Dimethyl-4,4'-bipyridinium;1,1'-Dimethyl-4,4'-bipyridinium cation;Dimethyl viologen;Methyl viologendication;Methyl viologen ion(2+);Methyl viologen(2+);N,N'-Dimethyl-4,4'-bipyridinium;N,N'-Dimethyl-4,4'-bipyridinium dication;Paraquat dication;Paraquat ion;Spraytop-graze;Starfire;Paraquat dichloride;
EINECS(EC#)225-141-7
Molecular FormulaC12H14N2
Molecular Weight186.256
Chemical Properties
Appearanceoff-white powder
storage tempKeep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(a)
Safety Data

Hazard T:Toxic
Risk R26/27/28
Safety

Hazard Codes:?ToxicT
Risk Statements: 26/27/28?
R26/27/28:Very toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 1-13-45?
S1 :Keep locked up.?
S13:Keep away from food, drink and animal foodstuffs.?
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: 2781
HazardClass: 6.1(a)
PackingGroup: II


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LD50 oral 35mg/kg (35mg/kg) ? Iyakuhin Kenkyu. Study of Medical Supplies. Vol. 10, Pg. 520, 1979.
chicken LD50 oral 262mg/kg (262mg/kg) ? Pesticide Manual. Vol. 9, Pg. 646, 1991.
dog LD50 oral 25mg/kg (25mg/kg) ? Iyakuhin Kenkyu. Study of Medical Supplies. Vol. 10, Pg. 520, 1979.
guinea pig LD50 oral 30mg/kg (30mg/kg) ? Iyakuhin Kenkyu. Study of Medical Supplies. Vol. 10, Pg. 520, 1979.
mammal (species unspecified) LD50 oral 70mg/kg (70mg/kg) ? Pesticide Manual. Vol. 9, Pg. 646, 1991.
man LDLo oral 171mg/kg (171mg/kg) LUNGS, THORAX, OR RESPIRATION: "FIBROSIS, FOCAL (PNEUMOCONIOSIS)"

GASTROINTESTINAL: CHANGE IN STRUCTURE OR FUNCTION OF ESOPHAGUS

GASTROINTESTINAL: ULCERATION OR BLEEDING FROM STOMACH
Journal of Toxicology, Clinical Toxicology. Vol. 26, Pg. 35, 1988.
man LDLo oral 200mg/kg (200mg/kg) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION

KIDNEY, URETER, AND BLADDER: RENAL FUNCTION TESTS DEPRESSED
Medical Journal of Australia. Vol. 158, Pg. 28, 1993.
man LDLo oral 343mg/kg (343mg/kg) GASTROINTESTINAL: CHANGE IN STRUCTURE OR FUNCTION OF ESOPHAGUS

KIDNEY, URETER, AND BLADDER: RENAL FUNCTION TESTS DEPRESSED

GASTROINTESTINAL: ULCERATION OR BLEEDING FROM STOMACH
Journal of Toxicology, Clinical Toxicology. Vol. 26, Pg. 35, 1988.
man LDLo oral 1690mg/kg (1690mg/kg) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION

GASTROINTESTINAL: ULCERATION OR BLEEDING FROM STOMACH

KIDNEY, URETER, AND BLADDER: RENAL FUNCTION TESTS DEPRESSED
Journal of Toxicology, Clinical Toxicology. Vol. 26, Pg. 35, 1988.
mouse LD50 oral 120mg/kg (120mg/kg) ? General Pharmacology. Vol. 14, Pg. 541, 1983.
mouse LD50 unreported 198mg/kg (198mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
Gigiena Naselennykh Mest. Hygiene in Populated Places. Vol. 17, Pg. 37, 1978.
rabbit LD50 skin 236mg/kg (236mg/kg) ? Pesticide Manual. Vol. 9, Pg. 646, 1991.
rat LD50 intraperitoneal 14800ug/kg (14.8mg/kg) LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA

LIVER: OTHER CHANGES

GASTROINTESTINAL: OTHER CHANGES
Veterinary and Human Toxicology. Vol. 22, Pg. 395, 1980.
rat LD50 oral 100mg/kg (100mg/kg) ? Iyakuhin Kenkyu. Study of Medical Supplies. Vol. 10, Pg. 520, 1979.
rat LD50 unreported 250mg/kg (250mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
Gigiena Naselennykh Mest. Hygiene in Populated Places. Vol. 17, Pg. 37, 1978.

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