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Methane, trinitro- cas no:517-25-9

Synonyms: Nitroform(6CI);Nitroform (explosive);Trinitromethane

Identification
NameMethane, trinitro-
CAS517-25-9
SynonymsNitroform(6CI);Nitroform (explosive);Trinitromethane
EINECS(EC#)208-236-8
Molecular FormulaCH N3 O6
Molecular Weight151.05
Chemical Properties
refractive index1.501
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass1.1A
Safety Data

Safety

Poison by ingestion and intraperitoneal routes. Moderately toxic by inhalation. Irritating to skin, eyes, and mucous membranes. Inhalation can cause headache and nausea. Causes mild narcosis. A very dangerous explosion hazard; explodes when heated rapidly. Dissolution is exothermic and solutions of more than 50% can explode. Mixtures of 90% trinitromethane + 10% isopropyl alcohol in polyethylene bottles have exploded. Frozen mixtures with 2-propanol (10%) explode when thawed. Can explode during distillation. Mixtures with divinyl ketone can explode at 4°C. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS.
RIDADR: 0473
HazardClass: 1.1A


Toxicity
1.    

orl-mus LDLo:300 mg/kg

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,93.
2.    

ihl-mus LC50:800 mg/m3/2H

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,93.
3.    

ipr-mus LD50:115 mg/kg

    KHFZAN    Khimiko-Farmatsevticheskii Zhurnal. Chemical Pharmaceutical Journal. 10 (6)(1976),53.

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