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4-Methylaminophenol sulfate cas no:55-55-0

Synonyms: Metol; 4-(Methylamino)phenol sulphate; 4-(Methylamino)phenol hemisulfate salt; Bis(4-hydroxy-N-methylanilinium) sulphate~Metol; METOL(TM); METHOL; BIS-(N-METHYL-4-HYDROXYANILINIUM) SULFATE; ARMOL; ELON; ECOL(R); GENOL

Identification
Name4-Methylaminophenol sulfate
CAS55-55-0
SynonymsMetol; 4-(Methylamino)phenol sulphate; 4-(Methylamino)phenol hemisulfate salt; Bis(4-hydroxy-N-methylanilinium) sulphate~Metol; METOL(TM); METHOL; BIS-(N-METHYL-4-HYDROXYANILINIUM) SULFATE; ARMOL; ELON; ECOL(R); GENOL
EINECS(EC#)200-237-1
Molecular Formula2(C7H9NO)?H2SO4
Molecular Weight344.38
Chemical Properties
Appearancewhite crystalline powder
storage temp−20°C
Sensitive Air Sensitive
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1
Safety Data

Hazard Xn:Harmful;N:Dangerousfortheenvironment;
Risk R22;R43;R48/22;R50/53
Safety

Poison by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of SOx and NOx.
Hazard Codes: Xn, N 
Risk Statements: 22-43-48/22-50/53 
R22: Harmful if swallowed. 
R43: May cause sensitization by skin contact. 
R48/22: Harmful: danger of serious damage to health by prolonged exposure if swallowed. 
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 36/37-46-60-61 
S36/37: Wear suitable protective clothing and gloves. 
S46: If swallowed, seek medical advice immediately and show this container or label. 
S60: This material and its container must be disposed of as hazardous waste. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
RTECS: SL8650000
HazardClass: 6.1
PackingGroup: III


HS Code 29222900

Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 skin > 1gm/kg (1000mg/kg)   Kodak Company Reports. Vol. 21MAY1971,
guinea pig LD50 unreported 1585mg/kg (1585mg/kg) BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(9), Pg. 87, 1984.
mouse LD50 oral 565mg/kg (565mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL: TREMOR
KIDNEY, URETER, AND BLADDER: OTHER CHANGES IN URINE COMPOSITION
National Technical Information Service. Vol. OTS0570966,
mouse LD50 unreported 769mg/kg (769mg/kg) BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)
BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(9), Pg. 87, 1984.
rat LD50 unreported 705mg/kg (705mg/kg) BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)
BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(9), Pg. 87, 1984.
rat LDLo intraperitoneal 50mg/kg (50mg/kg)   Kodak Company Reports. Vol. 21MAY1971,
rat LDLo oral 200mg/kg (200mg/kg)   Kodak Company Reports. Vol. 21MAY1971,

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