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Methylene bis(thiocyanate) cas no:6317-18-6

Synonyms: Methylenethiocyanate;Methylenedirhodanide;NSC 40464;Nalco 5793;Nalco D 2303;NalflocN 206;Proxel MB;Slimicide MC;V 709;WT 307B;Thiocyanicacid, methylene ester (6CI,7CI,8CI,9CI);Antiblu 3737;Antiblu 3738;Basiment540;Bis(thiocyanato)methane;Busan 110;Dithiocyanomethane;Kilstain;MBT;Metasol T 10;Methylene bis(thiocyanate);

Identification
NameMethylene bis(thiocyanate)
CAS6317-18-6
SynonymsMethylenethiocyanate;Methylenedirhodanide;NSC 40464;Nalco 5793;Nalco D 2303;NalflocN 206;Proxel MB;Slimicide MC;V 709;WT 307B;Thiocyanicacid, methylene ester (6CI,7CI,8CI,9CI);Antiblu 3737;Antiblu 3738;Basiment540;Bis(thiocyanato)methane;Busan 110;Dithiocyanomethane;Kilstain;MBT;Metasol T 10;Methylene bis(thiocyanate);
EINECS(EC#)228-652-3
Molecular FormulaC3H2N2S2
Molecular Weight130.191
Chemical Properties
Appearanceyellow crystalline powder
refractive index1.6
storage tempKeep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass8
Safety Data

Hazard T+:Verytoxic;N:Dangerousfortheenvironment;
Risk R25;R26;R34;R43;R50
Safety

Safety Information of?Methylene dithiocyanate (CAS NO.6317-18-6):
Hazard Codes: N ,T+
Risk Statements: 23/24/25-36/37-50-43-34-26-25
23/24/25: Toxic by inhalation, in contact with skin and if swallowed
36/37: Irritating to eyes and respiratory system
25: Toxic if swallowed.
26: Very toxic by inhalation.
34: Causes burns.
43: May cause sensitization by skin contact.
50: Very toxic to aquatic organisms.
Safety Statements: 26-28-36/37/39-45-61
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
28A: After contact with skin, wash immediately with plenty of water.
36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
61: Avoid release to the environment. Refer to special instructions/safety data sheets.
RIDADR: UN 2811 6.1/PG 2
WGK Germany: 3
RTECS: XL1560000
HazardClass: 8
PackingGroup: II
Poison by ingestion, intravenous, and subcutaneous routes. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also THIOCYANATES.


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 3600ug/kg (3.6mg/kg) ? U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03787,
rabbit LDLo skin 398mg/kg (398mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LIVER: OTHER CHANGES
National Technical Information Service. Vol. OTS0545751,
rabbit LDLo subcutaneous 20mg/kg (20mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION
Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 150, Pg. 257, 1930.
rat LD50 oral 55mg/kg (55mg/kg) ? Developments in Industrial Microbiology. Vol. 12, Pg. 404, 1971.

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