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Diethyl sulfate cas no:64-67-5

Synonyms: Diethylsulfate,98%; Diethyl sulphate; Sulphuric acid diethyl ester

Identification
NameDiethyl sulfate
CAS64-67-5
SynonymsDiethylsulfate,98%; Diethyl sulphate; Sulphuric acid diethyl ester
EINECS(EC#)200-589-6
Molecular FormulaC4H10O4S
Molecular Weight154.18
Chemical Properties
AppearanceClear oily liquid
refractive index1.399-1.401
storage tempRefrigerator (+4°C)
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1
Safety Data

Hazard T:Toxic;
Risk R20/21/22;R34;R45;R46
Safety

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by inhalation and subcutaneous routes. Moderately toxic by ingestion and skin contact. A severe skin irritant. An experimental teratogen. Mutation data reported. Combustible when exposed to heat or flame; can react with oxidizing materials. Moisture causes liberation of H2SO4. Violent reaction with potassium tert-butoxide. Reacts violently with 3,8-dinitro-6-phenylphenanthridine + water. Reaction with iron + water forms explosive hydrogen gas. To fight fire, use alcohol foam, H2O foam, CO2, dry chemicals. When heated to decomposition it emits toxic fumes of SOx. See also SULFATES.
Hazard Codes:  T
T:  Toxic
Risk Statements:  45-46-20/21/22-34
45:  May cause cancer
46:  May cause heritable genetic damage
20/21/22:  Harmful by inhalation, in contact with skin and if swallowed
34:  Causes burns
Safety Statements:  53-45
53:  Avoid exposure - obtain special instructions before use
45:  In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)
HazardClass:  6.1


Toxicity
1.    

skn-rbt 10 mg/24H SEV

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 31 (1949),60.
2.    

skn-rbt 500 mg open MLD

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 12/30 ,1971.
3.    

eye-rbt 2 mg SEV

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 31 (1949),60.
4.    

mmo-sat 5 mg/plate

    MUREAV    Mutation Research. 57 (1978),141.
5.    

mma-sat 5 mg/plate

    MUREAV    Mutation Research. 57 (1978),141.
6.    

slt-mus-ipr 100 mg/kg/10W

    MUREAV    Mutation Research. 75 (1980),63.
7.    

cyt-mus-ipr 150 mg/kg

    MUREAV    Mutation Research. 75 (1980),63.
8.    

msc-ham:ovr 1 mmol/L

    MUREAV    Mutation Research. 57 (1978),217.
9.    

ivn-rat TDLo:85 mg/kg (15D preg):CAR

    IARCCD    IARC Scientific Publications. 4 (1973),45.
10.    

orl-rat LD50:880 mg/kg

    JIDHAN    Journal of Industrial Hygiene. 31 (1949),60.
11.     <

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