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Methanol cas no:67-56-1

Synonyms: Alcohol, methyl;Carbinol;Methanol cluster;Bieleski's solution;Methyl alcohol;Wood alcohol;

Identification
NameMethanol
CAS67-56-1
SynonymsAlcohol, methyl;Carbinol;Methanol cluster;Bieleski's solution;Methyl alcohol;Wood alcohol;
EINECS(EC#)200-659-6
Molecular FormulaCH4O
Molecular Weight32.05
Chemical Properties
AppearanceClear, colorless liquid
refractive index1.328-1.330
storage tempStore at RT.
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass3
Safety Data

Hazard Xn: Harmful;T: Toxic;F: Flammable;
Risk R11;R23/24/25;R39/23/24/25
Safety

Hazard Codes of Methanol (CAS NO.67-56-1):?HarmfulXn,?ToxicT,?FlammableF
Risk Statements: 10-20/21/22-68/20/21/22-39/23/24/25-23/24/25-11-40-36-36/38-23/25
R10:Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R68:Possible risk of irreversible effects.
R39:Danger of very serious irreversible effects.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R11:Highly flammable.
R40:Limited evidence of a carcinogenic effect.
R36:Irritating to eyes.
R36/38:Irritating to eyes and skin.
R23/25:Toxic by inhalation and if swallowed.
Safety Statements: 36/37-7-45-16-24/25-23-24
S36/37:Wear suitable protective clothing and gloves.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S16:Keep away from sources of ignition.
S24/25:Avoid contact with skin and eyes.
S23:Do not breathe vapour.
S24:Avoid contact with skin.
RIDADR: UN 1170 3/PG 2
WGK Germany: 1
RTECS: PC1400000
F: 3-10
HazardClass: 3
PackingGroup: II


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LCLo inhalation 44gm/m3/6H (44000mg/m3) BEHAVIORAL: FOOD INTAKE (ANIMAL)

BEHAVIORAL: MUSCLE WEAKNESS

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
Archiv fuer Gewerbepathologie und Gewerbehygiene. Vol. 5, Pg. 1, 1933.
cat LDLo intravenous 4641mg/kg (4641mg/kg) ? Journal of Pharmacology and Experimental Therapeutics. Vol. 16, Pg. 1, 1920.
dog LDLo oral 7500mg/kg (7500mg/kg) ? "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1365, 1935.
frog LDLo parenteral 59gm/kg (59000mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
Archives Internationales de Pharmacodynamie et de Therapie. Vol. 50, Pg. 296, 1935.
guinea pig LD50 intraperitoneal 3556mg/kg (3556mg/kg) ? EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985.
hamster LD50 intraperitoneal 8555mg/kg (8555mg/kg) ? EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985.
human LDLo oral 143mg/kg (143mg/kg) SENSE ORGANS AND SPECIAL SENSES: OPTIC NERVE NEUROPATHY: EYE

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: NAUSEA OR VOMITING
"Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 382, 1969.
human LDLo oral 428mg/kg (428mg/kg) BEHAVIORAL: HEADACHE

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 74, 1974.
human TCLo inhalation 300ppm (300ppm) SENSE ORGANS AND SPECIAL SENSES: VISUAL FIELD CHANGES: EYE

BEHAVIORAL: HEADACHE

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 74, 1974.
human TCLo inhalation 86000mg/m3 (86000mg/m3) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LUNGS, THORAX, OR RESPIRATION: COUGH
Archiv fuer Gewerbepathologie und Gewerbehygiene. Vol. 5, Pg. 1, 1933.
man LDLo oral 6422mg/kg (6422mg/kg) BRAIN AND COVERINGS: "CHANGES IN CIRCULATION (HEMORRHAGE, THROMBOSIS, ETC.)"

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: NAUSEA OR VOMITING
Canadian Medical Association Journal. Vol. 128, Pg. 14, 1983.
man LDLo unreported 868mg/kg (868mg/kg) ? "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970.
man TDLo oral 3571uL/kg (3.571mL/kg) SENSE ORGANS AND SPECIAL SENSES: VISUAL FIELD CHANGES: EYE

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

BLOOD: OTHER CHANGES
Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 35, Pg. 2095, 1993.
man TDLo oral 9450uL/kg (9.45mL/kg) SENSE ORGANS AND SPECIAL SENSES: MYDRIASIS (PUPILLARY DILATION): EYE

BEHAVIORAL: GENERAL ANESTHETIC
American Journal of Emergency Medicine. Vol. 16, Pg. 538, 1998.
man TDLo oral 3429mg/kg (3429mg/kg) SENSE ORGANS AND SPECIAL SENSES: VISUAL FIELD CHANGES: EYE Acta Medica Scandinavica. Vol. 212, Pg. 5, 1982.
monkey LCLo inhalation 1000ppm (1000ppm) ? Industrial and Engineering Chemistry. Vol. 23, Pg. 931, 1931.
monkey LD50 oral 7gm/kg (7000mg/kg) BEHAVIORAL: MUSCLE WEAKNESS

BEHAVIORAL: ATAXIA

BEHAVIORAL: COMA
Toxicology and Applied Pharmacology. Vol. 3, Pg. 202, 1961.
monkey LDLo skin 393mg/kg (393mg/kg) ? Industrial and Engineering Chemistry. Vol. 23, Pg. 931, 1931.
mouse LCLo inhalation 50gm/m3/2H (50000mg/m3) ? "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 80, 1982.
mouse LD50 intraperitoneal 10765mg/kg (10765mg/kg) ? EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985.
mouse LD50 intravenous 4710mg/kg (4710mg/kg) ? EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985.
mouse LD50 oral 7300mg/kg (7300mg/kg) ? Toxicology. Vol. 25, Pg. 271, 1982.
mouse LD50 subcutaneous 9800mg/kg (9800mg/kg) ? Toxicology and Applied Pharmacology. Vol. 18, Pg. 185, 1971.
rabbit LD50 intraperitoneal 1826mg/kg (1826mg/kg) ? EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985.
rabbit LD50 intravenous 8907mg/kg (8907mg/kg) ? EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985.
rabbit LD50 oral 14200mg/kg (14200mg/kg) ? FAO Nutrition Meetings Report Series. Vol. 48A, Pg. 105, 1970.
rabbit LD50 skin 15800mg/kg (15800mg/kg) ? Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 74, 1974.
rat LC50 inhalation 64000ppm/4H (64000ppm) ? Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 74, 1974.
rat LD50 intraperitoneal 7529mg/kg (7529mg/kg) ? EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985.
rat LD50 intravenous 2131mg/kg (2131mg/kg) ? EHP, Environmental Health Perspectives. Vol. 61, Pg. 321, 1985.
rat LD50 oral 5628mg/kg (5628mg/kg) ? Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 19(11), Pg. 27, 1975.
women TDLo oral 4gm/kg (4000mg/kg) SENSE ORGANS AND SPECIAL SENSES: VISUAL FIELD CHANGES: EYE

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: NAUSEA OR VOMITING
Acta Medica Scandinavica. Vol. 212, Pg. 5, 1982.

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