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1-Propyne, 3,3'-oxybis- cas no:6921-27-3

Synonyms: 2-Propynylether (6CI,7CI,8CI); 3-[(Prop-2-ynyl)oxy]propyne; 4-Oxa-1,6-heptadiyne;Bis(2-propynyl) ether; Dipropargyl ether; Dipropargyl oxide; Propargyl ether

Identification
Name1-Propyne, 3,3'-oxybis-
CAS6921-27-3
Synonyms2-Propynylether (6CI,7CI,8CI); 3-[(Prop-2-ynyl)oxy]propyne; 4-Oxa-1,6-heptadiyne;Bis(2-propynyl) ether; Dipropargyl ether; Dipropargyl oxide; Propargyl ether
Molecular FormulaC6H6 O
Molecular Weight94.12
Chemical Properties
refractive index1.442
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass3.1
Safety Data

Hazard Xn
Risk R10;R19;R22
Safety

Poison by ingestion. Forms thermally unstable explosive peroxides in air. When heated to decomposition it emits acrid smoke and irritating fumes. See also ACETYLENE COMPOUNDS and ALKYNES and ETHERS.
Hazard CodesHarmfulXn,Xi
Risk Statements 10-19-22
R10:Flammable. 
R19: 2-Propynyl ether (CAS NO.6921-27-3) may form explosive peroxides. 
R22:Harmful if swallowed.
Safety Statements 16-36
S16:Keep away from sources of ignition. 
S36:Wear suitable protective clothing.
RIDADR UN 3271 3/PG 3
WGK Germany 3
RTECS UK5950000
Hazard Note Irritant
HazardClass 3.1
PackingGroup II


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LD50 oral 913mg/kg (913mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
GASTROINTESTINAL: NAUSEA OR VOMITING
LIVER: "HEPATITIS, FIBROUS (CIRRHOSIS, POST-NECROTIC SCARRING)"
Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 19, Pg. 389, 1960.
rabbit LD50 oral 168mg/kg (168mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL: FOOD INTAKE (ANIMAL)
LIVER: "HEPATITIS, FIBROUS (CIRRHOSIS, POST-NECROTIC SCARRING)"
Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 19, Pg. 389, 1960.
rat LD50 oral 539mg/kg (539mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL: FOOD INTAKE (ANIMAL)
LIVER: "HEPATITIS, FIBROUS (CIRRHOSIS, POST-NECROTIC SCARRING)"
Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 19, Pg. 389, 1960.

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