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Methanesulfenamide,1,1-dichloro-N-[(dimethylamino)sulfonyl]-1-fluoro-N-(4-methylphenyl)- cas no:731-27-1

Synonyms: Sulfamide,N-[(dichlorofluoromethyl)thio]-N',N'-dimethyl-N-p-tolyl- (7CI,8CI); BAY 5712a;Bayer 5712a; Dichlofluanid-methyl; Euparen M; Euparen Multi; Folicur multi;GORI 28; Melody Multi;N-Dichlorofluoromethylthio-N',N'-dimethyl-N-p-tolylsulfamide;N'-Dichlorofluoromethylthio-N,N-dimethyl-N'(p-tolyl)sulfamide; Preventol A 5S;Tolilfluanide; Tolylfluanid; Tolylfluanide

Identification
NameMethanesulfenamide,1,1-dichloro-N-[(dimethylamino)sulfonyl]-1-fluoro-N-(4-methylphenyl)-
CAS731-27-1
SynonymsSulfamide,N-[(dichlorofluoromethyl)thio]-N',N'-dimethyl-N-p-tolyl- (7CI,8CI); BAY 5712a;Bayer 5712a; Dichlofluanid-methyl; Euparen M; Euparen Multi; Folicur multi;GORI 28; Melody Multi;N-Dichlorofluoromethylthio-N',N'-dimethyl-N-p-tolylsulfamide;N'-Dichlorofluoromethylthio-N,N-dimethyl-N'(p-tolyl)sulfamide; Preventol A 5S;Tolilfluanide; Tolylfluanid; Tolylfluanide
EINECS(EC#)211-986-9
Molecular FormulaC10H13 Cl2 F N2 O2 S2
Molecular Weight347.27
Chemical Properties
refractive index1.606
storage temp0-6°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(b)
Safety Data

Hazard T,N
Risk 23-36/37/38-43-48/20-50/53
Safety

Poison by ingestion. Moderately toxic by skin contact. When heated to decomposition it emits very toxic fumes of Cl, F, NOx, and SOx.
Hazard Codes ToxicT,DangerousN
Risk Statements 23-36/37/38-43-48/20-50/53
R23 :Toxic by inhalation. 
R36/37/38:Irritating to eyes, respiratory system and skin. 
R43:May cause sensitization by skin contact.
R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 24-26-37-38-45-60-61
S24:Avoid contact with skin. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S37:Wear suitable gloves. 
S38:In case of insufficient ventilation, wear suitable respiratory equipment. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR 2588
RTECS WO6560000
HazardClass 6.1(b)
PackingGroup III


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
bird - domestic LD50 oral 1gm/kg (1000mg/kg)   "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 5, Pg. 225, 1976.
guinea pig LD50 oral 250mg/kg (250mg/kg)   "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976Vol. -, Pg. -, 1971/1976.
mouse LD50 oral 1gm/kg (1000mg/kg)   Pesticide Science. Vol. 4, Pg. -, 1973.
quail LD50 unreported > 5gm/kg (5000mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C131, 1991.
rabbit LD50 oral 500mg/kg (500mg/kg)   "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 5, Pg. 225, 1976.
rat LC50 inhalation 300mg/m3/4H (300mg/m3)   Pesticide Manual. Vol. 9, Pg. 827, 1991.
rat LD50 oral 1gm/kg (1000mg/kg)   Guide to the Chemicals Used in Crop Protection. Vol. 6, Pg. 505, 1973.
rat LD50 skin 500mg/kg (500mg/kg)   Guide to the Chemicals Used in Crop Protection. Vol. 6, Pg. 505, 1973.
rat LD50 subcutaneous 500mg/kg (500mg/kg)   Pesticide Science. Vol. 4, Pg. -, 1973.

 

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