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Chlorobromomethane cas no:74-97-5

Synonyms: bromochloromethane; Bromochloromethane CB; CBM; halon 1011; Methylene Chlorobromide; mil-b-4394-b; monochloromonobromomethane

Identification
NameChlorobromomethane
CAS74-97-5
Synonymsbromochloromethane; Bromochloromethane CB; CBM; halon 1011; Methylene Chlorobromide; mil-b-4394-b; monochloromonobromomethane
EINECS(EC#)200-826-3
Molecular FormulaCH2BrCl
Molecular Weight129.38
Chemical Properties
Appearancewhite to light yellow crystal powder
refractive index1.482-1.484
storage temp2-8°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(b)
Safety Data

Hazard Xn:Harmful
Risk R20;R36/37/38;R59
Safety

Mildly toxic by ingestion and inhalation. Mutation data reported. This material has a narcotic action of moderate intensity, although of prolonged duration. Animals exposed for several weeks to 1000?ppm had blood bromide levels as high as 350?mg/100?g. Therefore, until further data are available, it should be considered at least as toxic as carbon tetrachloride and more than minimal exposure to its vapors should be avoided. Dangerous; when heated to decomposition it emits highly toxic fumes of Br? and Cl?.
Hazard Codes:??Xi,N,XnT,F
Risk Statements:? 37/38-41-59-36/37/38-20-39/23/24/25-23/24/25-11?
R37/38:Irritating to respiratory system and skin.?
R41:Risk of serious damage to the eyes.?
R59:Dangerous to the ozone layer.?
R36/37/38:Irritating to eyes, respiratory system and skin.?
R20:Harmful by inhalation.?
R39:Danger of very serious irreversible effects.?
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.?
R11:Highly flammable.
Safety Statements:? 26-39-59-37/39-45-36/37?
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S39:Wear eye / face protection.?
S59:Refer to manufacturer / supplier for information on recovery / recycling.?
S37/39:Wear suitable gloves and eye/face protection.?
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S36/37:Wear suitable protective clothing and gloves.
RIDADR:? UN 1887 6.1/PG 3
WGK Germany:? 2
RTECS:? PA5250000
Hazard Note:? Irritant
HazardClass:? 6.1(b)
PackingGroup:? III


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 12030mg/m3/7H (12030mg/m3) BEHAVIORAL: GENERAL ANESTHETIC

BEHAVIORAL: MUSCLE WEAKNESS

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Journal of Industrial Hygiene and Toxicology. Vol. 29, Pg. 382, 1947.
mouse LD50 oral 4300mg/kg (4300mg/kg) BEHAVIORAL: GENERAL ANESTHETIC Journal of Industrial Hygiene and Toxicology. Vol. 29, Pg. 382, 1947.
rabbit LD50 skin > 20gm/kg (20000mg/kg) ? National Technical Information Service. Vol. AD-A062-138,
rat LCLo inhalation 28800ppm/15M (28800ppm) BEHAVIORAL: GENERAL ANESTHETIC

BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)

BEHAVIORAL: TREMOR
U.S. Army, Chemical Corps Medical Laboratories Research Reports. Vol. #113, Pg. 1952,
rat LD50 oral 5gm/kg (5000mg/kg) ? "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 390, 1969

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