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Methyl sulfide cas no:75-18-3

Synonyms: Dimethyl sulfide; Methylsulfide,99%; Dimethyl sulphide; 2-Thiapropane; Dimethyl Sulfide 10%; DMS; Methyl thioether; Methylthiomethane; thiobismethane; Thiopropane

Identification
NameMethyl sulfide
CAS75-18-3
SynonymsDimethyl sulfide; Methylsulfide,99%; Dimethyl sulphide; 2-Thiapropane; Dimethyl Sulfide 10%; DMS; Methyl thioether; Methylthiomethane; thiobismethane; Thiopropane
EINECS(EC#)200-846-2
Molecular FormulaC2H6S
Molecular Weight62.13
Chemical Properties
Appearanceclear colorless liquid
refractive index1.4351
storage temp2-8°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass3
Safety Data

Hazard F:Flammable
Risk R11;R22;R36
Safety

Poison by inhalation. Moderately toxic by ingestion. A skin and severe eye irritant. A very dangerous fire hazard when exposed to heat or flame. Explosive in the form of vapor when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits highly toxic fumes of SOx and may explode.
Hazard Codes:?F,Xn
Risk Statements:?11-22-37/38-41-36
R11:Highly flammable.?
R22:Harmful if swallowed.?
R37/38:Irritating to respiratory system and skin.?
R41:Risk of serious damage to the eyes.?
R36:Irritating to eyes.
Safety Statements:?7-9-16-29-33-36/39-26
S7:Keep container tightly closed.?
S9:Keep container in a well-ventilated place.?
S16:Keep away from sources of ignition.?
S29:Do not empty into drains.?
S33:Take precautionary measures against static discharges.?
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR:?UN 1164 3/PG 2
WGK Germany:? 1
F: 13
HazardClass:?3
PackingGroup:?II


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mammal (species unspecified) LD50 unreported 1950mg/kg (1950mg/kg) ? Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 16(6), Pg. 46, 1972.
mouse LC50 inhalation 31620ug/m3 (31.62mg/m3) ? Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 16(6), Pg. 46, 1972.
mouse LD50 intraperitoneal 8gm/kg (8000mg/kg) ? International Journal of Radiation Biology and Related Studies in Physics, Chemistry and Medicine. Vol. 3, Pg. 41, 1961.
mouse LD50 oral 3700mg/kg (3700mg/kg) BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)

BEHAVIORAL: ANTIPSYCHOTIC
Food and Cosmetics Toxicology. Vol. 17, Pg. 365, 1979.
rabbit LD50 skin > 5gm/kg (5000mg/kg) ? Food and Cosmetics Toxicology. Vol. 17, Pg. 365, 1979.
rat LC50 inhalation 40250ppm (40250ppm) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

KIDNEY, URETER, AND BLADDER: URINE VOLUME INCREASED
Personal Communication from H.B. Lackey, Chemical Products Div., Crown Zellerbach, Camas, WA 98607, June 9, 1978Vol. 09JUN1978,
rat LD50 oral 3300mg/kg (3300mg/kg) BEHAVIORAL: GENERAL ANESTHETIC

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)

BEHAVIORAL: IRRITABILITY
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 32(3), Pg. 3, 1967.

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