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Arsinic acid,As,As-dimethyl- cas no:75-60-5

Synonyms: Arsineoxide, hydroxydimethyl- (7CI,8CI); Arsinic acid, dimethyl- (9CI); Cacodylicacid (6CI); Ansar 138; Arsan; Dimethylarsenic acid; Dimethylarsinic acid;Hydroxydimethylarsine oxide; NSC 103115; NSC 71157; NSC 71158; Phytar; Silvisar510; Sylvicor

Identification
NameArsinic acid,As,As-dimethyl-
CAS75-60-5
SynonymsArsineoxide, hydroxydimethyl- (7CI,8CI); Arsinic acid, dimethyl- (9CI); Cacodylicacid (6CI); Ansar 138; Arsan; Dimethylarsenic acid; Dimethylarsinic acid;Hydroxydimethylarsine oxide; NSC 103115; NSC 71157; NSC 71158; Phytar; Silvisar510; Sylvicor
EINECS(EC#)200-883-4
Molecular FormulaC2H7 As O2
Molecular Weight137.9974
Chemical Properties
Appearancecolorless or white crystalline powder
storage tempStore at RT.
Sensitive Hygroscopic
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1
Safety Data

Hazard TN
Risk R23/25
Safety

Poison by an unspecified route. Moderately toxic by ingestion and intraperitoneal routes. Experimental teratogenic and reproductive effects. A skin and eye irritant. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Used as an herbicide, defoliant, and silvicide. Hazardous when water solution is in contact with active metals, e.g., Fe, Al, Zn. When heated to decomposition it emits toxic fumes of As. See also ARSINE and ARSENIC COMPOUNDS.
Hazard Codes:
T: Toxic 
N: Dangerous for the environment
Risk Statements:
R23/25: Toxic by inhalation and if swallowed.  
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
Safety Statements:
S20/21: When using, do not eat or drink and do not smoke. 
S28: After contact with skin, wash immediately with plenty of soap-suds.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60: This material and its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 1572 6.1/PG 2
WGK Germany: 3
RTECS: CH7525000
F:
F 3: Hygroscopic.
F 10: Keep under argon.
HazardClass: 6.1
PackingGroup: II


Toxicity
Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 500mg/kg (500mg/kg)   National Technical Information Service. Vol. AD295-864,
mouse LD50 oral 1200mg/kg (1200mg/kg)   Journal of Agricultural and Food Chemistry. Vol. 45, Pg. 449, 1997.
mouse LD50 unreported 185mg/kg (185mg/kg)   "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 393, 1971.
rat LCLo inhalation > 2600mg/m3/2H (2600mg/m3)   Toxicology and Applied Pharmacology. Vol. 37, Pg. 165, 1976.
rat LD50 oral 644mg/kg (644mg/kg)   Fundamental and Applied Toxicology. Vol. 7, Pg. 299, 1986.

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