Hazard C:Corrosive
Risk R14/15;R25;R34
Safety
Poison by inhalation. A severe eye, skin, and mucous membrane irritant. Upon contact with moisture, lithium hydroxide is formed. The LiOH formed is very caustic and therefore highly toxic, particularly to lungs and respiratory tract, skin, and mucous membranes. The powder ignites spontaneously in air. The solid can ignite spontaneously in moist air. Mixtures of the powder with liquid oxygen are explosive. Ignites on contact with dinitrogen oxide, oxygen + moisture. To fight fire, use special mixtures of dry chemical. See also LITHIUM COMPOUNDS and HYDRIDES.
Hazard Codes:
F,
C,
T
Risk Statements: 14-34-25-14/15
R14: Reacts violently with water
R34: Causes burns
R25: Toxic if swallowed
R14/15: Reacts violently with water, liberating extremely flammable gases
Safety Statements: 16-26-27-36/37/39-7/8-45-25
S16: Keep away from sources of ignition - No smoking
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27: Take off immediately all contaminated clothing
S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S25: Avoid contact with eyes
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S7/8: Keep container tightly closed and dry