Hazard C:Corrosive
Risk R14;R34;R37;R40
Safety
Probably highly toxic. A corrosive irritant to the eyes, skin, and mucous membranes. Will react with water, steam, or acids to produce heat, toxic and corrosive fumes. Violent reaction or ignition with calcium hydroxide + sodium carbonate, phenylpropanol, sulfuric acid, oleum, fluorosulfuric acid, chlorosulfuric acid, 1,1,1-tris(hydroxymethyl)methane, water, potassium, sodium, RuO4. When heated to decomposition it emits very toxic fumes of Br? and POx. See also PHOSPHIDES and BROMIDES.
Hazard Codes of Phosphorus tribromide (CAS NO.7789-60-8):?
C
Risk Statements: 34-37-40-14?
R34: Causes burns.?
R37: Irritating to respiratory system?
R40: Limited evidence of a carcinogenic effect.?
R14: Reacts violently with water.
Safety Statements:?26-45-36/37/39?
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 3264 8/PG 2
WGK Germany: 2
RTECS: TH4460000
F: 21
HazardClass: 8
PackingGroup: II