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Phosphorothioic acid,O-[2-(ethylthio)ethyl] O,O-dimethyl ester cas no:867-27-6

Synonyms: Phosphorothioicacid, O-[2-(ethylthio)ethyl] O,O-di-Me ester (6CI); Benzenesulfenic acid, 4-(ethylthio)-,anhydride with dimethyl hydrogen phosphite; Demeton-O-methyl; Methyl-O-demeton;O,O-Dimethyl O-2-(ethylthio)ethyl phosphorothioate; O,O-DimethylO-[2-(ethylthio)ethyl] thiophosphate; O-[2-(Ethylthio)ethyl] O,O-dimethylphosphorothioate; O-[2-(Ethylthio)ethyl] O,O-dimethyl thiophosphate

Identification
NamePhosphorothioic acid,O-[2-(ethylthio)ethyl] O,O-dimethyl ester
CAS867-27-6
SynonymsPhosphorothioicacid, O-[2-(ethylthio)ethyl] O,O-di-Me ester (6CI); Benzenesulfenic acid, 4-(ethylthio)-,anhydride with dimethyl hydrogen phosphite; Demeton-O-methyl; Methyl-O-demeton;O,O-Dimethyl O-2-(ethylthio)ethyl phosphorothioate; O,O-DimethylO-[2-(ethylthio)ethyl] thiophosphate; O-[2-(Ethylthio)ethyl] O,O-dimethylphosphorothioate; O-[2-(Ethylthio)ethyl] O,O-dimethyl thiophosphate
EINECS(EC#)212-758-1
Molecular FormulaC6H15 O3 P S2
Molecular Weight230.30
Chemical Properties
refractive index1.505
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(b)
Safety Data

Hazard T: Toxic;
Risk 25
Safety

Poison by ingestion, skin contact, inhalation, and intravenous routes. Experimental teratogenic and reproductive effects. When heated to decomposition it emits very toxic fumes of POx and SOx. See also DEMETON-O + DEMETON-S and DEMETON; DEMETON-O-METHYL SULFOXIDE; DEMETON-S; DEMETON-S-METHYL; DEMETON-S-METHYL-SULPHONE.
 

Hazard Codes of Demeton-O-methyl (CAS NO.867-27-6): ToxicT
Risk Statements: 25 
R25 :Toxic if swallowed.
Safety Statements: 24-36/37-45 
S24:Avoid contact with skin. 
S36/37:Wear suitable protective clothing and gloves. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)


Toxicity
1.    

orl-rat LD50:75 mg/kg

    FATOAO    Farmakologiya i Toksikologiya (Moscow). 22 (1959),559.
2.    

ivn-rat LD50:216 mg/kg

    BIJOAK    Biochemical Journal. 67 (1957),187.
3.    

orl-mus LD50:46 mg/kg

    FATOAO    Farmakologiya i Toksikologiya (Moscow). 22 (1959),559.
4.    

orl-cat LDLo:30 mg/kg

    FATOAO    Farmakologiya i Toksikologiya (Moscow). 22 (1959),559.
5.    

ihl-cat LCLo:20 mg/m3

    GISAAA    Gigiena i Sanitariya. 28 (3)(1963),21.
6.    

skn-rbt LDLo:75 mg/kg

    FATOAO    Farmakologiya i Toksikologiya (Moscow). 22 (1959),559.

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Address: 45-16 Ramsey Road, Shirley, NY 11967, USA

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