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1,3,5-Triazine-2,4-diamine,N2-(1,1-dimethylethyl)-N4-ethyl-6-(methylthio)- cas no:886-50-0

Synonyms: 1,3,5-Triazine-2,4-diamine,N-(1,1-dimethylethyl)-N'-ethyl-6-(methylthio)- (9CI);s-Triazine,2-(tert-butylamino)-4-(ethylamino)-6-(methylthio)- (7CI,8CI);2-Ethylamino-4-methylthio-6-tert-butylamino-1,3,5-triazine;2-Methylmercapto-4-ethylamino-6-tert-butylamino-1,3,5-triazine;2-Methylthio-4-ethylamino-6-tert-butylamino-s-triazine;2-Methylthio-4-tert-butylamino-6-ethylamino-s-triazine;2-tert-Butylamino-4-ethylamino-6-methylthio-s-triazine;4-Ethylamino-2-methylthio-6-tert-butylamino-1,3,5-triazine;6-tert-Butylamino-4-ethylamino-2-methylthio-1,3,5-triazine;A 1866;Clarosan;GS 14260;Igran;Igran 50;Igran 500;Prebane;Saterb;Terbutrex;Terbutryn;Terbutryne;tert-Butryn;

Identification
Name1,3,5-Triazine-2,4-diamine,N2-(1,1-dimethylethyl)-N4-ethyl-6-(methylthio)-
CAS886-50-0
Synonyms1,3,5-Triazine-2,4-diamine,N-(1,1-dimethylethyl)-N'-ethyl-6-(methylthio)- (9CI);s-Triazine,2-(tert-butylamino)-4-(ethylamino)-6-(methylthio)- (7CI,8CI);2-Ethylamino-4-methylthio-6-tert-butylamino-1,3,5-triazine;2-Methylmercapto-4-ethylamino-6-tert-butylamino-1,3,5-triazine;2-Methylthio-4-ethylamino-6-tert-butylamino-s-triazine;2-Methylthio-4-tert-butylamino-6-ethylamino-s-triazine;2-tert-Butylamino-4-ethylamino-6-methylthio-s-triazine;4-Ethylamino-2-methylthio-6-tert-butylamino-1,3,5-triazine;6-tert-Butylamino-4-ethylamino-2-methylthio-1,3,5-triazine;A 1866;Clarosan;GS 14260;Igran;Igran 50;Igran 500;Prebane;Saterb;Terbutrex;Terbutryn;Terbutryne;tert-Butryn;
EINECS(EC#)212-950-5
Molecular FormulaC10H19N5S
Molecular Weight241.35
Chemical Properties
Appearancesolid
refractive index1.55
storage tempAPPROX 4°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1
Safety Data

Hazard Xi,N,Xn,F
Risk R36
Safety Moderately toxic by ingestion, intraperitoneal and possibly other routes. A skin and eye irritant. An herbicide. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also MERCAPTANS and AMINES.

Toxicity

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XY4725000
CHEMICAL NAME :
s-Triazine, 2-(tert-butylamino)-4-(ethylamino)-6-(methylthio)-
CAS REGISTRY NUMBER :
886-50-0
LAST UPDATED :
199710
DATA ITEMS CITED :
16
MOLECULAR FORMULA :
C10-H19-N5-S
MOLECULAR WEIGHT :
241.40
WISWESSER LINE NOTATION :
T6N CN ENJ BS1 DMX1&1&1 FM2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
CIGET* Ciba-Geigy Toxicology Data/Indexes. (Ciba-Geigy Corp., 556 Morris Ave., Summit, NJ 07901) Volume(issue)/page/year: -,-,1977
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
CIGET* Ciba-Geigy Toxicology Data/Indexes. (Ciba-Geigy Corp., 556 Morris Ave., Summit, NJ 07901) Volume(issue)/page/year: -,-,1977 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2045 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PESTD5 Proceedings of the European Society of Toxicology. (Amsterdam, Netherlands) V.16-18, 1975-77. Discontinued. Volume(issue)/page/year: 17,351,1976
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>8 gm/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A384,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,799,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
699 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PESTD5 Proceedings of the European Society of Toxicology. (Amsterdam, Netherlands) V.16-18, 1975-77. Discontinued. Volume(issue)/page/year: 17,351,1976
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3884 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PESTD5 Proceedings of the European Society of Toxicology. (Amsterdam, Netherlands) V.16-18, 1975-77. Discontinued. Volume(issue)/page/year: 17,351,1976
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
554 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PESTD5 Proceedings of the European Society of Toxicology. (Amsterdam, Netherlands) V.16-18, 1975-77. Discontinued. Volume(issue)/page/year: 17,351,1976
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>10200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CIGET* Ciba-Geigy Toxicology Data/Indexes. (Ciba-Geigy Corp., 556 Morris Ave., Summit, NJ 07901) Volume(issue)/page/year: -,-,1977
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
4 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A384,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
2900 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,438,1971 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2462 No. of Facilities: 13 (estimated) No. of Industries: 1 No. of Occupations: 9 No. of Employees: 567 (estimated) No. of Female Employees: 13 (estimated)

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