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Phosphorothioic acid,S-[2-(ethylthio)ethyl] O,O-dimethyl ester cas no:919-86-8

Synonyms: Phosphorothioicacid, S-[2-(ethylthio)ethyl] O,O-di-Me ester (6CI); Demeton-S-methyl; Metaisoseptox;Metaisosystox; Metasystox 55; Metasystox I; Metasystox J; Methyl demetonthioester; Methyl isosystox; Methylthionodemeton; O,O-DimethylS-2-(ethylthio)ethyl phosphorothioate; S-[2-(Ethylthio)ethyl] O,O-dimethylphosphorothioate; S-[2-(Ethylthio)ethyl] O,O-dimethyl thiophosphate; Thiometonoxon

Identification
NamePhosphorothioic acid,S-[2-(ethylthio)ethyl] O,O-dimethyl ester
CAS919-86-8
SynonymsPhosphorothioicacid, S-[2-(ethylthio)ethyl] O,O-di-Me ester (6CI); Demeton-S-methyl; Metaisoseptox;Metaisosystox; Metasystox 55; Metasystox I; Metasystox J; Methyl demetonthioester; Methyl isosystox; Methylthionodemeton; O,O-DimethylS-2-(ethylthio)ethyl phosphorothioate; S-[2-(Ethylthio)ethyl] O,O-dimethylphosphorothioate; S-[2-(Ethylthio)ethyl] O,O-dimethyl thiophosphate; Thiometonoxon
EINECS(EC#)213-052-6
Molecular FormulaC6H15 O3 P S2
Molecular Weight230.30
Chemical Properties
refractive index1.496
storage temp-18°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(a)
Safety Data

Hazard T,N,Xn,F
Risk 24/25-51/53-36-20/21/22-11
Safety

Poison by ingestion, inhalation, skin contact, intraperitoneal, and intravenous routes. Mutation data reported. An insecticide. When heated to decomposition it emits very toxic fumes of POx and SOx. See also DEMETON-O + DEMETON-S and DEMETON; DEMETON-O-METHYL; DEMETON-O-METHYL SULFOXIDE; DEMETON-S; DEMETON-S-METHYL-SULPHONE.
Safety Information of Demeton-S-methyl (CAS NO.919-86-8):
Hazard Codes: TToxic,NDangerous,XnHarmful,FFlammable
Risk Statements:  24/25-51/53-36-20/21/22-11 
11:  Highly Flammable
20:  Harmful by inhalation 
21:  Harmful in contact with skin 
22:  Harmful if swallowed 
24:  Toxic in contact with skin 
25:  Toxic if swallowed 
36:  Irritating to the eyes 
51:  Toxic to aquatic organisms  
53:  May cause long-term adverse effects in the aquatic environment 
Safety Statements: 28-36/37-45-61-26
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 
36:  Wear suitable protective clothing  
37:  Wear suitable gloves 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
61:  Avoid release to the environment. Refer to special instructions safety data sheet 


Toxicity
1.    

mmo-sat 5 µL/plate

    MUREAV    Mutation Research. 28 (1975),405.
2.    

sln-dmg-orl 80 ppm

    MUREAV    Mutation Research. 28 (1975),405.
3.    

orl-rat LD50:30 mg/kg

    FMCHA2    Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1991,C197.
4.    

ihl-rat LC50:500 mg/m3/4H

    85DPAN    Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow,Berlin, Germany.: Verlag Paul Parey,1971/76.
5.    

skn-rat LD50:85 mg/kg

    PHJOAV    Pharmaceutical Journal. 185 (1960),361.
6.    

ipr-rat LD50:7500 µg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 4 (1962),621.
7.    

ivn-rat LDLo:54 mg/kg

    BCPCA6    Biochemical Pharmacology. 6 (1961),244.
8.    

orl-gpg LD50:110 mg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 4 (1962),621.
9.    

ipr-gpg LD50:12,500 µg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 4 (1962),621.

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