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Ethyl methyl ketone oxime cas no:96-29-7

Synonyms: 2-Butanone oxime; 2-butoxime; aron m 1; butanone oxime; ethyl methyl ketoxime

Identification
NameEthyl methyl ketone oxime
CAS96-29-7
Synonyms2-Butanone oxime; 2-butoxime; aron m 1; butanone oxime; ethyl methyl ketoxime
EINECS(EC#)202-496-6
Molecular FormulaC4H9NO
Molecular Weight87.12
Chemical Properties
AppearanceClear liquid
refractive index1.441-1.444
storage tempStore in a cool, dry place. Keep container closed when not in use.
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass3
Safety Data

Hazard Xn:Harmful;
Risk R21;R40;R41;R43
Safety

Safety Information of Methyl ethyl ketoxime (CAS NO.96-29-7):
Hazard Codes: Xn ,T
Risk Statements: 21-40-41-43-52/53-48/25 
R21: Harmful in contact with skin. 
R40: Limited evidence of a carcinogenic effect. 
R41: Risk of serious damage to the eyes. 
R43: May cause sensitization by skin contact. 
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R48: Danger of serious damage to health by prolonged exposure.
R25: Toxic if swallowed.
Safety Statements:13-23-26-36/37/39-61-45-25 
S13: Keep away from food, drink and animal foodstuffs. 
S23: Do not breathe vapour. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S25: Avoid contact with eyes.
RIDADR:UN 1993 3/PG 3
WGK Germany:1
RTECS:EL9275000
HazardClass:3
PackingGroup:III
HS Code:29280090
Poison by intraperitoneal route. Moderately toxic by subcutaneous route. May explode if heated. Reacts with sulfuric acid to form an explosive product. When heated to decomposition it emits toxic fumes of NOx.


HS Code 29280090

Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 200mg/kg (200mg/kg)   National Technical Information Service. Vol. AD277-689,
mouse LD50 oral 1gm/kg (1000mg/kg)   National Technical Information Service. Vol. OTS0524679,
rabbit LD50 skin 200uL/kg (0.2mL/kg)   National Technical Information Service. Vol. OTS0529835,
rat LC inhalation > 50gm/m3/4H (50000mg/m3) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) National Technical Information Service. Vol. OTS0524693,
rat LD skin > 2gm/kg (2000mg/kg)   National Technical Information Service. Vol. OTS0530016,
rat LD50 oral 930mg/kg (930mg/kg)   Office of Toxic Substances Report. Vol. OTS,
rat LD50 subcutaneous 2702mg/kg (2702mg/kg)   Nagoya Journal of Medical Science. Vol. 29, Pg. 393, 1967.

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