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Tri-n-butylphosphine cas no:998-40-3

Synonyms: TBUP; Tributylphosphinetech; Zukunft nur als S15-5801 Tri-n-butylphosphine; Trinbutylphosphinemincolorlesslightyellowliq; Trinbutylphosphineinhexane; Tributylphosphane

Identification
NameTri-n-butylphosphine
CAS998-40-3
SynonymsTBUP; Tributylphosphinetech; Zukunft nur als S15-5801 Tri-n-butylphosphine; Trinbutylphosphinemincolorlesslightyellowliq; Trinbutylphosphineinhexane; Tributylphosphane
EINECS(EC#)213-651-2
Molecular FormulaC12H27P
Molecular Weight202.32
Chemical Properties
Appearanceclear liquid
refractive index1.461-1.463
storage temp2-8°C
Sensitive Moisture Sensitive/Air Sensitive
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass4.2
Safety Data

Hazard F:Flammable;C:Corrosive;
Risk R11;R17;R21/22;R34
Safety

Safety Information of Tributylphosphine (CAS NO.998-40-3):
Hazard Codes:Xi  ,F  ,C
Risk Statements:36/38-34-21/22-17-11-37
36/38:Irritating to eyes and skin
11:Highly flammable
17:Spontaneously flammable in air
21/22:Harmful in contact with skin and if swallowed
34:Causes burns
Safety Statements:41-36/37/39-26-16-45-43-17-5
41:In case of fire and/or explosion do not breathe fumes
16:Keep away from sources of ignition - No smoking
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39:Wear suitable protective clothing, gloves and eye/face protection
43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
17:Keep away from combustible material
5:Keep contents under ... (appropriate liquid to be specified by the manufacturer)
RIDADR:UN 3254 4.2/PG 1
WGK Germany:3
RTECS:SZ3270000
F:10-13-23
HazardClass:4.2
PackingGroup:I
Moderately toxic by ingestion. Slightly toxic by skin contact. When heated to decomposition it emits toxic vapors of POx.


Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LD50 skin 2gm/kg (2000mg/kg)   "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 600, 1969.
rat LD50 oral 750mg/kg (750mg/kg)   "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 600, 1969.

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