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Bis(triphenylphosphine)nickel(II)chloride cas no:14264-16-5

Synonyms: Dichlorobis(triphenylphosphine)nickel(II); [Bis(triphenylphosphine)]dichloroNickel(II);

Identification
NameBis(triphenylphosphine)nickel(II)chloride
CAS14264-16-5
SynonymsDichlorobis(triphenylphosphine)nickel(II); [Bis(triphenylphosphine)]dichloroNickel(II);
EINECS(EC#)238-154-8
Molecular FormulaC36H30Cl2NiP2
Molecular Weight654.18
Chemical Properties
Appearancedark gray solid.
storage tempStore in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket.
Sensitive Hygroscopic
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(b)
Safety Data

Hazard T:Toxic;
Risk R20/21/22;R34;R45
Safety

The safety information of Bis(triphenylphosphine)dichloronickel (CAS NO.14264-16-5) is as follows:
Hazard Codes: T
Risk Statements: 45-43-52/53-34-20/21/22
45: May cause cancer
43: May cause sensitization by skin contact
52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
34: Causes burns
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements: 53-36/37-45-60-36/37/39-26
53: Avoid exposure - obtain special instruction before use
36/37: Wear suitable protective clothing and gloves
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
60: This material and/or its container must be disposed of as hazardous waste
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
RIDADR: 3260
WGK Germany: 3
RTECS: QR6170000
HazardClass: 6.1(b)
PackingGroup: III
F: 21
Confirmed human carcinogen. Poison by intravenous route. See also NICKEL COMPOUNDS. When heated to decomposition it emits very toxic fumes of Cl− and POx.


HS Code 29310095

Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 56mg/kg (56mg/kg)   U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03119,

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