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Bis(triphenylphosphine)nickel(II)chloride cas no:14264-16-5

Synonyms: Dichlorobis(triphenylphosphine)nickel(II); [Bis(triphenylphosphine)]dichloroNickel(II);

Identification
NameBis(triphenylphosphine)nickel(II)chloride
CAS14264-16-5
SynonymsDichlorobis(triphenylphosphine)nickel(II); [Bis(triphenylphosphine)]dichloroNickel(II);
EINECS(EC#)238-154-8
Molecular FormulaC36H30Cl2NiP2
Molecular Weight654.18
Chemical Properties
Appearancedark gray solid.
storage tempStore in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket.
Sensitive Hygroscopic
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(b)
Safety Data

Hazard T:Toxic;
Risk R20/21/22;R34;R45
Safety

The safety information of Bis(triphenylphosphine)dichloronickel (CAS NO.14264-16-5) is as follows:
Hazard Codes: T
Risk Statements: 45-43-52/53-34-20/21/22
45: May cause cancer
43: May cause sensitization by skin contact
52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
34: Causes burns
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements: 53-36/37-45-60-36/37/39-26
53: Avoid exposure - obtain special instruction before use
36/37: Wear suitable protective clothing and gloves
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
60: This material and/or its container must be disposed of as hazardous waste
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
RIDADR: 3260
WGK Germany: 3
RTECS: QR6170000
HazardClass: 6.1(b)
PackingGroup: III
F: 21
Confirmed human carcinogen. Poison by intravenous route. See also NICKEL COMPOUNDS. When heated to decomposition it emits very toxic fumes of Cl and POx.


HS Code 29310095

Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 56mg/kg (56mg/kg)   U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03119,

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