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Carbonochloridicacid, 2-propen-1-yl ester cas no:2937-50-0

Synonyms: Carbonochloridicacid, 2-propenyl ester (9CI);Formic acid, chloro-, allyl ester (6CI,7CI,8CI);2-Propen-1-yl chloroformate;2-Propenyl chloroformate;Allyl carbonochloridate;Allyloxycarbonyl chloride;Chloroformic acid allyl ester;

Identification
NameCarbonochloridicacid, 2-propen-1-yl ester
CAS2937-50-0
SynonymsCarbonochloridicacid, 2-propenyl ester (9CI);Formic acid, chloro-, allyl ester (6CI,7CI,8CI);2-Propen-1-yl chloroformate;2-Propenyl chloroformate;Allyl carbonochloridate;Allyloxycarbonyl chloride;Chloroformic acid allyl ester;
EINECS(EC#)220-916-6
Molecular FormulaC4H5ClO2
Molecular Weight120.5
Chemical Properties
AppearanceA colorless liquid with a pungent odor.
refractive indexn20/D 1.422(lit.)
storage temp2-8°C
Globally Harmonized System of Classification adn Labelling of Chemicals(GHS)
Hazardclass6.1(b)
Safety Data

Hazard T+: Very toxic;
Risk R10
Safety Poison by inhalation and ingestion. Corrosive. Dangerous when exposed to heat, open flame (or sparks), or powerful oxidizers. Can react with oxidizing materials. To fight fire, use alcohol foam, spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of Cl?. See also ALLYL COMPOUNDS and ESTERS.

Toxicity

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ5775000
CHEMICAL NAME :
Formic acid, chloro-, allyl ester
CAS REGISTRY NUMBER :
2937-50-0
BEILSTEIN REFERENCE NO. :
0773915
LAST UPDATED :
199710
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C4-H5-Cl-O2
MOLECULAR WEIGHT :
120.54
WISWESSER LINE NOTATION :
GVO2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
244 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),51,1984
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
32400 ug/m3
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),51,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
210 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),51,1984
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
23100 ug/m3
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),51,1984 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1230 ug/m3/30D-I
TOXIC EFFECTS :
Cardiac - EKG changes not diagnostic of specified effects Liver - fatty liver degeneration Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),51,1984 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.4 mg/m3;Skin JAN 1993

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